Photocatalytic hydrogen(H2)evolution via water spilling over semiconductors has been considered to be one of the most promising strategies for sustainable energy supply in the future to provide non-pollution and renew...Photocatalytic hydrogen(H2)evolution via water spilling over semiconductors has been considered to be one of the most promising strategies for sustainable energy supply in the future to provide non-pollution and renewable energy.The key to efficient conversion of solar-chemical energy is the design of an efficient structure for high charge separation and transportation.Therefore,cocatalysts are necessary in boosting photocatalytic H2 evolution.To date,semiconductor photocatalysts have been modified by various cocatalysts due to the extended light harvest,enhanced charge carrier separation efficiency and improved stability.This review focuses on recent developments of cocatalysts in photocatalytic H2 evolution,the roles and mechanism of the cocatalysts are discussed in detail.The cocatalysts can be divided into the following categories:metal/alloy cocatalysts,metal phosphides cocatalysts,metal oxide/hydroxide cocatalysts,carbon-based cocatalysts,dual cocatalysts,Z-scheme cocatalysts and MOFs cocatalysts.The future research and forecast for photocatalytic hydrogen generation are also suggested.展开更多
The design and construction of low‐cost and high‐performance hybrid materials for the photocatalytic hydrogen production reaction(HER)are extremely important for the large‐scale application of hydrogen energy.Metal...The design and construction of low‐cost and high‐performance hybrid materials for the photocatalytic hydrogen production reaction(HER)are extremely important for the large‐scale application of hydrogen energy.Metal‐organic frameworks(MOFs)are considered to be potential photocatalytic materials.Herein,monodisperse,small size,non‐precious metal transition metal phosphide Ni2P is encapsulated into a typical MOF(UiO‐66‐NH2)as a hybrid core‐shell cocatalyst to modify Zn_(0.5)Cd_(0.5)S for photocatalytic hydrogen production.Ni2P is wrapped in UiO‐66‐NH_(2)via an in situ solvothermal method,and Zn_(0.5)Cd_(0.5)S sulfide is decorated with a core‐shell Ni_(2)P@UiO‐66‐NH_(2)cocatalyst to obtain ternary Ni_(2)P@UiO‐66‐NH_(2)/Zn_(0.5)Cd_(0.5)S composite materials.Photoelectric and chemical characterization confirms that the ternary composites have good kinetic hydrogen production performance.The hydrogen production rate of 10%10 mg Ni_(2)P@UiO‐66‐NH_(2)/Zn_(0.5)Cd_(0.5)S reaches 40.91 mmol·g^(–1)·h^(–1)with an apparent quantum efficiency at 420 nm of 13.57%.The addition of 10 mg Ni_(2)P@UiO‐66‐NH_(2)increases the surface area of the ternary material,providing abundant reaction sites and forming an efficient charge transfer channel,which is conducive to efficient hydrogen production by the ternary photocatalysts.It is shown that the formation of a ternary composite system is beneficial to the occurrence of an efficient catalytic reaction.This study provides a new perspective for the construction of high‐performance photocatalytic materials.展开更多
Photocatalysis is considered a prospective way to alleviate the energy crisis and environmental pollution.It is therefore extremely important to design highly efficient photocatalysts for catalytic systems.In recent y...Photocatalysis is considered a prospective way to alleviate the energy crisis and environmental pollution.It is therefore extremely important to design highly efficient photocatalysts for catalytic systems.In recent years,hollow‐structured materials have attracted considerable interest for application in energy conversion fields owing to their large specific surface areas,improved light absorption,and shortened charge carrier transfer path.Because they contain inner and outer surfaces,hollow‐structured materials can provide a superior platform for the deposition of other components.A number of hollow‐structured hierarchical systems have been designed and fabricated in recent decades.It is important to rationally design and construct complex hierarchical structures.In this review,general preparation approaches for hollow‐structured materials are presented,followed by a summary of the recent synthesis methods and mechanisms of typical hollow‐structured materials for applications in the photocatalytic field.Complex hollow‐structured hierarchical photocatalysts are classified into two types,hollow cocatalyst‐based and hollow host photocatalyst‐based,and the design principle and analysis of the photocatalytic reaction mechanism for photocatalytic H2 evolution and CO_(2) reduction are also introduced.The effects of hollow‐structured materials have also been investigated.This review provides a reference for the rational construction of advanced,highly efficient photocatalytic materials.展开更多
在应用型人才培养需要、工程教育认证要求的背景下,材料类专业开设《计算机在材料科学中的应用》课程极其重要。该课程是培养学生具备满足工程教育认证提出的“毕业要求5:使用现代工具”能力的重要支撑课程。本文深入分析了以往本校乃...在应用型人才培养需要、工程教育认证要求的背景下,材料类专业开设《计算机在材料科学中的应用》课程极其重要。该课程是培养学生具备满足工程教育认证提出的“毕业要求5:使用现代工具”能力的重要支撑课程。本文深入分析了以往本校乃至其他高校开设此门课程在教学实践过程中所存在的问题,作出课程教改与实践探索,通过教改和教学实践探索,设定了课程目标,优化了课程内容,革新了教学实践过程,打造出适合于应用型人才培养、符合工程教育认证要求的《计算机在材料科学中的应用》课程。探索形成的相关结果和规律不仅能够为开设有此门课程的高校提供参考还能为相近课程的教授提供教改借鉴,起到辐射示范作用。Under the background of the need for application-oriented personnel training and the requirements of engineering education certification, it is extremely important for materials majors to offer the course “Application of Computer in Materials Science”. This course is an important supporting course to train students to meet the “graduation requirement 5: Using modern tools” proposed by the Engineering Education certification. This paper makes an in-depth analysis of the problems existing in the teaching practice of this course offered by the university and other universities in the past, and makes curriculum reform and practice exploration. Through the teaching reform and teaching practice exploration, the course objectives are set, the course content is optimized, and the teaching practice process is reformed. The course “Application of Computer in Materials Science”, which is suitable for the training of applied talents and meets the requirements of engineering education certification, has been created. The relevant results and rules formed by the exploration can not only provide reference for the universities offering this course, but also provide teaching reform reference for professors of similar courses, and play a radiation demonstration role.展开更多
基金financially supported by the National Natural Science Foundation of China(51572295,21273285 and 21003157)Beijing Nova Program(2008B76)Science Foundation of China University of Petroleum,Beijing(KYJJ2012-06-20 and 2462016YXBS05)~~
文摘Photocatalytic hydrogen(H2)evolution via water spilling over semiconductors has been considered to be one of the most promising strategies for sustainable energy supply in the future to provide non-pollution and renewable energy.The key to efficient conversion of solar-chemical energy is the design of an efficient structure for high charge separation and transportation.Therefore,cocatalysts are necessary in boosting photocatalytic H2 evolution.To date,semiconductor photocatalysts have been modified by various cocatalysts due to the extended light harvest,enhanced charge carrier separation efficiency and improved stability.This review focuses on recent developments of cocatalysts in photocatalytic H2 evolution,the roles and mechanism of the cocatalysts are discussed in detail.The cocatalysts can be divided into the following categories:metal/alloy cocatalysts,metal phosphides cocatalysts,metal oxide/hydroxide cocatalysts,carbon-based cocatalysts,dual cocatalysts,Z-scheme cocatalysts and MOFs cocatalysts.The future research and forecast for photocatalytic hydrogen generation are also suggested.
文摘The design and construction of low‐cost and high‐performance hybrid materials for the photocatalytic hydrogen production reaction(HER)are extremely important for the large‐scale application of hydrogen energy.Metal‐organic frameworks(MOFs)are considered to be potential photocatalytic materials.Herein,monodisperse,small size,non‐precious metal transition metal phosphide Ni2P is encapsulated into a typical MOF(UiO‐66‐NH2)as a hybrid core‐shell cocatalyst to modify Zn_(0.5)Cd_(0.5)S for photocatalytic hydrogen production.Ni2P is wrapped in UiO‐66‐NH_(2)via an in situ solvothermal method,and Zn_(0.5)Cd_(0.5)S sulfide is decorated with a core‐shell Ni_(2)P@UiO‐66‐NH_(2)cocatalyst to obtain ternary Ni_(2)P@UiO‐66‐NH_(2)/Zn_(0.5)Cd_(0.5)S composite materials.Photoelectric and chemical characterization confirms that the ternary composites have good kinetic hydrogen production performance.The hydrogen production rate of 10%10 mg Ni_(2)P@UiO‐66‐NH_(2)/Zn_(0.5)Cd_(0.5)S reaches 40.91 mmol·g^(–1)·h^(–1)with an apparent quantum efficiency at 420 nm of 13.57%.The addition of 10 mg Ni_(2)P@UiO‐66‐NH_(2)increases the surface area of the ternary material,providing abundant reaction sites and forming an efficient charge transfer channel,which is conducive to efficient hydrogen production by the ternary photocatalysts.It is shown that the formation of a ternary composite system is beneficial to the occurrence of an efficient catalytic reaction.This study provides a new perspective for the construction of high‐performance photocatalytic materials.
文摘Photocatalysis is considered a prospective way to alleviate the energy crisis and environmental pollution.It is therefore extremely important to design highly efficient photocatalysts for catalytic systems.In recent years,hollow‐structured materials have attracted considerable interest for application in energy conversion fields owing to their large specific surface areas,improved light absorption,and shortened charge carrier transfer path.Because they contain inner and outer surfaces,hollow‐structured materials can provide a superior platform for the deposition of other components.A number of hollow‐structured hierarchical systems have been designed and fabricated in recent decades.It is important to rationally design and construct complex hierarchical structures.In this review,general preparation approaches for hollow‐structured materials are presented,followed by a summary of the recent synthesis methods and mechanisms of typical hollow‐structured materials for applications in the photocatalytic field.Complex hollow‐structured hierarchical photocatalysts are classified into two types,hollow cocatalyst‐based and hollow host photocatalyst‐based,and the design principle and analysis of the photocatalytic reaction mechanism for photocatalytic H2 evolution and CO_(2) reduction are also introduced.The effects of hollow‐structured materials have also been investigated.This review provides a reference for the rational construction of advanced,highly efficient photocatalytic materials.
文摘在应用型人才培养需要、工程教育认证要求的背景下,材料类专业开设《计算机在材料科学中的应用》课程极其重要。该课程是培养学生具备满足工程教育认证提出的“毕业要求5:使用现代工具”能力的重要支撑课程。本文深入分析了以往本校乃至其他高校开设此门课程在教学实践过程中所存在的问题,作出课程教改与实践探索,通过教改和教学实践探索,设定了课程目标,优化了课程内容,革新了教学实践过程,打造出适合于应用型人才培养、符合工程教育认证要求的《计算机在材料科学中的应用》课程。探索形成的相关结果和规律不仅能够为开设有此门课程的高校提供参考还能为相近课程的教授提供教改借鉴,起到辐射示范作用。Under the background of the need for application-oriented personnel training and the requirements of engineering education certification, it is extremely important for materials majors to offer the course “Application of Computer in Materials Science”. This course is an important supporting course to train students to meet the “graduation requirement 5: Using modern tools” proposed by the Engineering Education certification. This paper makes an in-depth analysis of the problems existing in the teaching practice of this course offered by the university and other universities in the past, and makes curriculum reform and practice exploration. Through the teaching reform and teaching practice exploration, the course objectives are set, the course content is optimized, and the teaching practice process is reformed. The course “Application of Computer in Materials Science”, which is suitable for the training of applied talents and meets the requirements of engineering education certification, has been created. The relevant results and rules formed by the exploration can not only provide reference for the universities offering this course, but also provide teaching reform reference for professors of similar courses, and play a radiation demonstration role.