星载单光子激光雷达在浅水域测深方面展现出巨大的潜力,但其接收到的点云数据中存在大量噪声,给高程信息的提取带来了困难。目前,基于OPTICS(Ordering Points to Identify the Clustering Structure)的去噪算法因其精度高,在强背景噪声...星载单光子激光雷达在浅水域测深方面展现出巨大的潜力,但其接收到的点云数据中存在大量噪声,给高程信息的提取带来了困难。目前,基于OPTICS(Ordering Points to Identify the Clustering Structure)的去噪算法因其精度高,在强背景噪声下表现良好,得到了广泛的应用,但此算法在水底附近区域存在去噪效果不佳的现象。为了解决这个问题,文章提出了一种参量自适应的OPTICS单光子点云去噪算法,该算法与现有OPTICS算法固定输入参数的方式不同,是通过场景自适应获取更合适的输入参数来保证水底附近区域光子的分布参数的测量准确性,从而提升水底附近区域的去噪效果。凝聚度结果显示,新算法在水底附近区域的去噪效果较现有OPTICS算法提升了约13.67%,可为之后的水深测量等工作提供更高精度的单光子点云图像。展开更多
Covalent organic frameworks(COFs)have lately emerged as a blooming class of potential materials for photocatalytic water splitting because of their high crystallinity,huge surface areas,and structural versatility.Howe...Covalent organic frameworks(COFs)have lately emerged as a blooming class of potential materials for photocatalytic water splitting because of their high crystallinity,huge surface areas,and structural versatility.However,the photocatalytic performance for most pure COFs face some limitations factors,such as the significant recombination of photogenerated carriers and slow charge transfer.Herein,a novel thioether-functionalized pyrene-based COF(S_(4)-COF)was effectively produced and chosen as a support for the immobilization of ultrafine gold nanoparticles(Au NPs).S_(4)-COF photocatalyst with Au as cocatalyst demonstrates remarkable photocatalytic activity with a H_(2) generation rate of 1377μmol g^(−1) h^(−1) under visible light(>420 nm),which is ca.4.5-fold increase comparing to that of pure S_(4)-COF(302μmol g^(−1) h^(−1)).Au NPs anchored on S_(4)-COF possess an ultrafine size distribution ranging from 1.75 to 6.25 nm with an average size centered at 3.8 nm,which benefits from the coordination interaction between thioether groups and Au.Meanwhile,the produced Au@S_(4)-COF can generate a stable photocatalytic H_(2) generation during the four recycles and preserve its crystallinity structure after the stability testing.The Au NPs anchored on the S_(4)-COF photocatalyst can greatly accelerate the separation of photogenerated carriers and increase charge transfer because of the combined function of Au NPs and thioether groups.Such a method can not only prevent the aggregation of Au NPs onto thioether-containing COFs to achieve long-term photostability but also allow uniform dispersion for an ordered structure of photocatalysts.This work provides a rational strategy for designing and preparing COF-based photocatalysts for solar-driven H_(2) production.展开更多
文摘星载单光子激光雷达在浅水域测深方面展现出巨大的潜力,但其接收到的点云数据中存在大量噪声,给高程信息的提取带来了困难。目前,基于OPTICS(Ordering Points to Identify the Clustering Structure)的去噪算法因其精度高,在强背景噪声下表现良好,得到了广泛的应用,但此算法在水底附近区域存在去噪效果不佳的现象。为了解决这个问题,文章提出了一种参量自适应的OPTICS单光子点云去噪算法,该算法与现有OPTICS算法固定输入参数的方式不同,是通过场景自适应获取更合适的输入参数来保证水底附近区域光子的分布参数的测量准确性,从而提升水底附近区域的去噪效果。凝聚度结果显示,新算法在水底附近区域的去噪效果较现有OPTICS算法提升了约13.67%,可为之后的水深测量等工作提供更高精度的单光子点云图像。
文摘Covalent organic frameworks(COFs)have lately emerged as a blooming class of potential materials for photocatalytic water splitting because of their high crystallinity,huge surface areas,and structural versatility.However,the photocatalytic performance for most pure COFs face some limitations factors,such as the significant recombination of photogenerated carriers and slow charge transfer.Herein,a novel thioether-functionalized pyrene-based COF(S_(4)-COF)was effectively produced and chosen as a support for the immobilization of ultrafine gold nanoparticles(Au NPs).S_(4)-COF photocatalyst with Au as cocatalyst demonstrates remarkable photocatalytic activity with a H_(2) generation rate of 1377μmol g^(−1) h^(−1) under visible light(>420 nm),which is ca.4.5-fold increase comparing to that of pure S_(4)-COF(302μmol g^(−1) h^(−1)).Au NPs anchored on S_(4)-COF possess an ultrafine size distribution ranging from 1.75 to 6.25 nm with an average size centered at 3.8 nm,which benefits from the coordination interaction between thioether groups and Au.Meanwhile,the produced Au@S_(4)-COF can generate a stable photocatalytic H_(2) generation during the four recycles and preserve its crystallinity structure after the stability testing.The Au NPs anchored on the S_(4)-COF photocatalyst can greatly accelerate the separation of photogenerated carriers and increase charge transfer because of the combined function of Au NPs and thioether groups.Such a method can not only prevent the aggregation of Au NPs onto thioether-containing COFs to achieve long-term photostability but also allow uniform dispersion for an ordered structure of photocatalysts.This work provides a rational strategy for designing and preparing COF-based photocatalysts for solar-driven H_(2) production.
