Over the past decades,there has been an intensive quest for theoretical studies and experimental detection of polynitrogen species (e.g.,N4,N5^+,N8,cyclo-N5^-,and polymeric nitrogen,etc.)that are potentiaUy stable in ...Over the past decades,there has been an intensive quest for theoretical studies and experimental detection of polynitrogen species (e.g.,N4,N5^+,N8,cyclo-N5^-,and polymeric nitrogen,etc.)that are potentiaUy stable in the condensed phase [1-4].As a class of representative polynitrogen species,cyclo-pentazolate (cyclo-N5^-)com- pounds have received significant interest from synthetic chemists.Despite traditional arylpentazole compounds were discovered in 1956 [5],the experimental synthesis of stable cyclo-N;species has encountered great difficulties for subsequent decades.展开更多
基金supported by the National Natural Science Foundation of China (21602211 and 11472251)the Thousand Talents Plan (Youth)+1 种基金Dvelopment Foundation of CAEP (2015B0302057 and 2015B0302056)the Science Challenge Project (TZ2018004)
文摘Over the past decades,there has been an intensive quest for theoretical studies and experimental detection of polynitrogen species (e.g.,N4,N5^+,N8,cyclo-N5^-,and polymeric nitrogen,etc.)that are potentiaUy stable in the condensed phase [1-4].As a class of representative polynitrogen species,cyclo-pentazolate (cyclo-N5^-)com- pounds have received significant interest from synthetic chemists.Despite traditional arylpentazole compounds were discovered in 1956 [5],the experimental synthesis of stable cyclo-N;species has encountered great difficulties for subsequent decades.
