Organic persistent room-temperature phosphorescent(RTP)materials are promising for applications requiring the secure recording and anti-counterfeiting features owing to their appealing optical properties.Several criti...Organic persistent room-temperature phosphorescent(RTP)materials are promising for applications requiring the secure recording and anti-counterfeiting features owing to their appealing optical properties.Several critical challenges,such as the difficulty to obtain high-quality patterns over large areas and low security levels,need to be addressed to meet the requirements for commercial purpose.Here,we prepared a series of quaternary phosphonium salts with different alkyl chains,which showed interesting organic persistent RTP.The ionic characteristics and the alkyl chains of these molecules impart abundant weak intermolecular interactions.This confers the molecules a high crystallinity,which helps to preserve the persistent RTP properties and cover large areas.Moreover,the RTP lifetime of these organic salts varies over a wide range(1.27 to 884.71 ms)and can be tuned by simply changing the alkyl chain length and counterions,which opens new possibilities in multi-level information encryption applications.It is believed that the engineering of organic salts with tunable persistent RTP lifetimes and large-area printing can promote early-stage demonstrations of security applications into mature commercialization.展开更多
基金supported by the National Funds for Distinguished Young Scientists(61825503)the National Natural Science Foundation of China(62288102,62205277 and 62322508).
基金financial support from the National Funds for Distinguished Young Scientists (61825503)the National Natural Science Foundation of China (62075101, 21701087 and 61775101)+1 种基金the National Program for Support of Top-Notch Young Professionalsthe Postgraduate Research & Practice Innovation Program of Jiangsu Province (46030CX18010)
文摘Organic persistent room-temperature phosphorescent(RTP)materials are promising for applications requiring the secure recording and anti-counterfeiting features owing to their appealing optical properties.Several critical challenges,such as the difficulty to obtain high-quality patterns over large areas and low security levels,need to be addressed to meet the requirements for commercial purpose.Here,we prepared a series of quaternary phosphonium salts with different alkyl chains,which showed interesting organic persistent RTP.The ionic characteristics and the alkyl chains of these molecules impart abundant weak intermolecular interactions.This confers the molecules a high crystallinity,which helps to preserve the persistent RTP properties and cover large areas.Moreover,the RTP lifetime of these organic salts varies over a wide range(1.27 to 884.71 ms)and can be tuned by simply changing the alkyl chain length and counterions,which opens new possibilities in multi-level information encryption applications.It is believed that the engineering of organic salts with tunable persistent RTP lifetimes and large-area printing can promote early-stage demonstrations of security applications into mature commercialization.
