A new lanthanide metal-organic framework (MOF)[Eu(BTB)(phen)(DMF)]·DMF (1,DMF=N,N-dimethylformamide) was synthesized using H_(3)BTB (1,3,5-tri(4-carboxyphenyl)benzene) and phen(1,10-phenanthroline) under solvothe...A new lanthanide metal-organic framework (MOF)[Eu(BTB)(phen)(DMF)]·DMF (1,DMF=N,N-dimethylformamide) was synthesized using H_(3)BTB (1,3,5-tri(4-carboxyphenyl)benzene) and phen(1,10-phenanthroline) under solvothermal conditions.The structure of the prepared MOF was characterized by single-crystal X-ray diffraction analyses,elemental analysis,fluorescence spectrum,FT-IR spectroscopy,powder X-ray diffraction and thermogravimetric analyses.The structure of 1 can be viewed as a 3-D supramolecular network,which is formed by the stacking of 2D layers throughπ-πinteraction.The luminescence explorations revealed that 1 possesses favorable selectivity and sensitivity for testing Fe^(3+).Additionally,color tuning was achieved by varying Eu^(3+):Tb^(3+)ratios in the reaction mixtures.展开更多
基金supported by the High-level Teachers in Beijing Municipal Universities in the Period of 13th Five-year Plan (CIT&TCD201904044)URT program of Beijing Institute of Petrochemical Technology (2020J00009)。
文摘A new lanthanide metal-organic framework (MOF)[Eu(BTB)(phen)(DMF)]·DMF (1,DMF=N,N-dimethylformamide) was synthesized using H_(3)BTB (1,3,5-tri(4-carboxyphenyl)benzene) and phen(1,10-phenanthroline) under solvothermal conditions.The structure of the prepared MOF was characterized by single-crystal X-ray diffraction analyses,elemental analysis,fluorescence spectrum,FT-IR spectroscopy,powder X-ray diffraction and thermogravimetric analyses.The structure of 1 can be viewed as a 3-D supramolecular network,which is formed by the stacking of 2D layers throughπ-πinteraction.The luminescence explorations revealed that 1 possesses favorable selectivity and sensitivity for testing Fe^(3+).Additionally,color tuning was achieved by varying Eu^(3+):Tb^(3+)ratios in the reaction mixtures.
