2-chloro-4,6-bis-naphthalen-2-yloxy-1,3,5-triazine(CDNTA) was synthesized by nucleophilic substitution reaction between cyanuric chloride and β-naphthol.The effects of the stuff molar ratio,the variety and dosage of ...2-chloro-4,6-bis-naphthalen-2-yloxy-1,3,5-triazine(CDNTA) was synthesized by nucleophilic substitution reaction between cyanuric chloride and β-naphthol.The effects of the stuff molar ratio,the variety and dosage of base,the solvents,the reaction time and temperature on the yields of CDNTA were investigated.The optimized reaction conditions included that cyanuric chloride and β-naphthol were mixed at the stoichiometric ratio,sodium hydroxide was used as base(its molar ratio to cyanuric chloride was 2.1:1),mixture of acetone and water(the volume ratio was 1:1) was used as solvent,the reaction was carried out in ice water bath for 2 h,then at 40 ℃ for 7 h.Under these conditions,the yield of CDNTA could reach 96.3%.The target compound was characterized by elementary analysis,IR spectrum,1 H-NMR and MS.The solubility,thermo stability,and UV spectrum of CDNTA were investigated.展开更多
Novel dendritic compounds G1.5(OH)4 and G1.5(OH)8 with peripheral hydroxyl were synthesized under mild conditions from eyanuric chloride, ethylene diamine, ethanolamine and diethanolamine. The products could be se...Novel dendritic compounds G1.5(OH)4 and G1.5(OH)8 with peripheral hydroxyl were synthesized under mild conditions from eyanuric chloride, ethylene diamine, ethanolamine and diethanolamine. The products could be separated and purified through dispersion and precipitation in organic solvents with good yields (over 93.0%) and high purity (above 98.0%, HPLC). The structures of the products were characterized by 1R, MS, 1H NMR and elementary analysis. G1.5(OH)4 and Gl.5(OH)8 could be dissolved in polar solvents such as methanol, water and dimethylsulfoxide. TGA analysis showed that G1.5(OH)4 and G1.5(OH)8 had good thermo stability. The aqueous solutions ofG1.5(OH)4 and G1.5(OH)8 exhibited low surface tension.展开更多
文摘2-chloro-4,6-bis-naphthalen-2-yloxy-1,3,5-triazine(CDNTA) was synthesized by nucleophilic substitution reaction between cyanuric chloride and β-naphthol.The effects of the stuff molar ratio,the variety and dosage of base,the solvents,the reaction time and temperature on the yields of CDNTA were investigated.The optimized reaction conditions included that cyanuric chloride and β-naphthol were mixed at the stoichiometric ratio,sodium hydroxide was used as base(its molar ratio to cyanuric chloride was 2.1:1),mixture of acetone and water(the volume ratio was 1:1) was used as solvent,the reaction was carried out in ice water bath for 2 h,then at 40 ℃ for 7 h.Under these conditions,the yield of CDNTA could reach 96.3%.The target compound was characterized by elementary analysis,IR spectrum,1 H-NMR and MS.The solubility,thermo stability,and UV spectrum of CDNTA were investigated.
基金Supporting information for this article is availaigle on the WWW under http://dx.doi.org/10.1002/cjoc.201100557 or from the author.Acknowledgement The authors are greateful for the financial supports from the National Natural Science Foundation of China (No. 21074085), the open research foundation of the National Engineering Laboratory for Modem Silk, Soochow University (No. SS115801) and the open research foundation of the Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University (No. KJS0911).
文摘Novel dendritic compounds G1.5(OH)4 and G1.5(OH)8 with peripheral hydroxyl were synthesized under mild conditions from eyanuric chloride, ethylene diamine, ethanolamine and diethanolamine. The products could be separated and purified through dispersion and precipitation in organic solvents with good yields (over 93.0%) and high purity (above 98.0%, HPLC). The structures of the products were characterized by 1R, MS, 1H NMR and elementary analysis. G1.5(OH)4 and Gl.5(OH)8 could be dissolved in polar solvents such as methanol, water and dimethylsulfoxide. TGA analysis showed that G1.5(OH)4 and G1.5(OH)8 had good thermo stability. The aqueous solutions ofG1.5(OH)4 and G1.5(OH)8 exhibited low surface tension.