1,2-（1-Acridin-10＇-yl-2-aza-2-methylprop-1,3-ylene）fullerene was synthesized firstly and characterized by UV-Vis, ^1H NMR, ^13C NMR and electrospray ionization mass spectroscopy, which is capable of forming a stabl...1,2-（1-Acridin-10＇-yl-2-aza-2-methylprop-1,3-ylene）fullerene was synthesized firstly and characterized by UV-Vis, ^1H NMR, ^13C NMR and electrospray ionization mass spectroscopy, which is capable of forming a stable complex with zinc tetraphenylporphyrin via the axial ligation. The steady state fluorescence studies show efficient quenching of the zinc tetraphenylporphyrin emission upon axial coordination of acridine attached to C60.展开更多
基金Project supported by the National Natural Science Foundation of China （Nos. 20271002, 20490217）, Excellent Young Scholar Foundation （No. 04046065） and the Natural Science Foundation of Anhui Province （No. 00045122）, the Scientific Research Foundation for the Returned 0verseas Chinese Scholars and Excellent Young Teachers Program of the Ministry of Education of China, and the Education Department of Anhui Province （Nos. 2001KJ 115ZD, 2006KJ006TD）.Acknowledgement The authors wish to thank Hu Ji-Ping and Yang Gao- Sheng for their assistance with NMR.
文摘1,2-（1-Acridin-10＇-yl-2-aza-2-methylprop-1,3-ylene）fullerene was synthesized firstly and characterized by UV-Vis, ^1H NMR, ^13C NMR and electrospray ionization mass spectroscopy, which is capable of forming a stable complex with zinc tetraphenylporphyrin via the axial ligation. The steady state fluorescence studies show efficient quenching of the zinc tetraphenylporphyrin emission upon axial coordination of acridine attached to C60.
