基于青海盐渍土地区埋地钢筋混凝土板现场模型试验,研究了考虑温度影响的盐渍土盐胀作用下钢筋混凝土板内及其表面的应力变化规律,并将其定义为“盐胀应力”。利用钢筋混凝土板内外应变监测结果,通过理论分析得出盐胀应力计算公式。基于...基于青海盐渍土地区埋地钢筋混凝土板现场模型试验,研究了考虑温度影响的盐渍土盐胀作用下钢筋混凝土板内及其表面的应力变化规律,并将其定义为“盐胀应力”。利用钢筋混凝土板内外应变监测结果,通过理论分析得出盐胀应力计算公式。基于Sum of sine函数模型将1年周期内盐胀应力的变化过程以及相对应的盐胀作用划分为发展阶段、稳定阶段、下降阶段3个阶段。其中发展阶段为每年10月至次年2月,温度变化范围为0~10℃,在该温度范围内,随着温度降低,盐胀应力不断增加,说明盐胀现象愈为强烈。对青海盐渍土地区的埋地结构物设计提出了建议,以期最大程度地减少盐渍土对埋地结构物的破坏。展开更多
Sub-micrometer ultra fine CeO2-ZrO2 mixed oxides have been prepared by milling solid cerium carbonate and zirconium oxy-chloride with ammonia and followed by filtering, drying and calcining procedures. The effects of ...Sub-micrometer ultra fine CeO2-ZrO2 mixed oxides have been prepared by milling solid cerium carbonate and zirconium oxy-chloride with ammonia and followed by filtering, drying and calcining procedures. The effects of Ce/Zr molar ratio, milling time and calcining temperature on the phase composition, particle size and morphology, surface charge, as well as the polishing property were investigated. The results show that the mixed oxide calcined at 1 000 ℃ is composed of cubic ceria doped with zirconium and tetragonal zirconia doped with cerium, and the phase composition varies with calcination temperature and the Ce/Zr molar ratio. The monoclinic zirconia is observed when decreasing calcination temperature and shortening milling time, demonstrating that milling and calcining can force the phase transformation from monoclinic zirconia to cerium stabilized tetragonal zirconia and zirconium doped cubic ceria solid solutions. The removal rate for the optical glass polishing varies with Ce/Zr molar ratio. A synergetic polishing effect is found when Ce/Zr molar ratio below 4, and the optimal Ce/Zr molar ratio is 1∶1. At the same time, the cubic ceria content, density, particle size and surface charge all increase when calcination temperature increasing from 800 ℃ to 1 100 ℃. However, the particle morphology changes from disperse quasi-sphere to irregular aggregation and the maximal removal rate for optical glass polishing lies at 1 000 ℃.These facts show that the polishing property of the synthesized ceria-zirconia mixed oxide is affected by the particle physical characteristics comprehensively.展开更多
文摘基于青海盐渍土地区埋地钢筋混凝土板现场模型试验,研究了考虑温度影响的盐渍土盐胀作用下钢筋混凝土板内及其表面的应力变化规律,并将其定义为“盐胀应力”。利用钢筋混凝土板内外应变监测结果,通过理论分析得出盐胀应力计算公式。基于Sum of sine函数模型将1年周期内盐胀应力的变化过程以及相对应的盐胀作用划分为发展阶段、稳定阶段、下降阶段3个阶段。其中发展阶段为每年10月至次年2月,温度变化范围为0~10℃,在该温度范围内,随着温度降低,盐胀应力不断增加,说明盐胀现象愈为强烈。对青海盐渍土地区的埋地结构物设计提出了建议,以期最大程度地减少盐渍土对埋地结构物的破坏。
文摘Sub-micrometer ultra fine CeO2-ZrO2 mixed oxides have been prepared by milling solid cerium carbonate and zirconium oxy-chloride with ammonia and followed by filtering, drying and calcining procedures. The effects of Ce/Zr molar ratio, milling time and calcining temperature on the phase composition, particle size and morphology, surface charge, as well as the polishing property were investigated. The results show that the mixed oxide calcined at 1 000 ℃ is composed of cubic ceria doped with zirconium and tetragonal zirconia doped with cerium, and the phase composition varies with calcination temperature and the Ce/Zr molar ratio. The monoclinic zirconia is observed when decreasing calcination temperature and shortening milling time, demonstrating that milling and calcining can force the phase transformation from monoclinic zirconia to cerium stabilized tetragonal zirconia and zirconium doped cubic ceria solid solutions. The removal rate for the optical glass polishing varies with Ce/Zr molar ratio. A synergetic polishing effect is found when Ce/Zr molar ratio below 4, and the optimal Ce/Zr molar ratio is 1∶1. At the same time, the cubic ceria content, density, particle size and surface charge all increase when calcination temperature increasing from 800 ℃ to 1 100 ℃. However, the particle morphology changes from disperse quasi-sphere to irregular aggregation and the maximal removal rate for optical glass polishing lies at 1 000 ℃.These facts show that the polishing property of the synthesized ceria-zirconia mixed oxide is affected by the particle physical characteristics comprehensively.
