The cross sections of the ls electron photoionization and corresponding shake-up processes for Li atoms in the ground state 1s^22s and excited states 1s^22p, 1s^23s, 1s^23p and 1s^23d are calculated using the multi-co...The cross sections of the ls electron photoionization and corresponding shake-up processes for Li atoms in the ground state 1s^22s and excited states 1s^22p, 1s^23s, 1s^23p and 1s^23d are calculated using the multi-configuration Dirac-Fock method. The latest experimental photoelectron spectrum at hv= 100 eV [Cubaynes D et al. Phys. Rev. Lett. 99 （2007） 213004] has been reproduced by the present theoretical investigation excellently. The relative intensity of the shake-up satellites shows that the effects of correlation and relaxation become more important for the higher excited states of the lithium atom, which are explained very well by the spatial overlap of the initial and final state wavefunctions. In addition, strong dependence of the cross section on the atomic orbitals of the valence electrons are found, especially near the threshold.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 10434100 and 10774122, the International Cooperation Programme of Science and Technology of China （CI-2004-07）, the Specialized Research Fund for the Doctoral Programme of Higher Education of China under Grant No 20070736001, and the Technology and Innovation Programme of Northwest Normal University under Grant No NWNU-KJCXGC-03-21.
文摘The cross sections of the ls electron photoionization and corresponding shake-up processes for Li atoms in the ground state 1s^22s and excited states 1s^22p, 1s^23s, 1s^23p and 1s^23d are calculated using the multi-configuration Dirac-Fock method. The latest experimental photoelectron spectrum at hv= 100 eV [Cubaynes D et al. Phys. Rev. Lett. 99 （2007） 213004] has been reproduced by the present theoretical investigation excellently. The relative intensity of the shake-up satellites shows that the effects of correlation and relaxation become more important for the higher excited states of the lithium atom, which are explained very well by the spatial overlap of the initial and final state wavefunctions. In addition, strong dependence of the cross section on the atomic orbitals of the valence electrons are found, especially near the threshold.
