The hydrothermal reactions of Cd（OAc）2·2H2O with 1,2,4,5-benzenetetracarboxylic acid（H4bta） and 1,4-bis（thiabendazolyl）butane（L1） or 1,6-bis（thiabendazolyl）hexane（L2） afforded two coordination polymer...The hydrothermal reactions of Cd（OAc）2·2H2O with 1,2,4,5-benzenetetracarboxylic acid（H4bta） and 1,4-bis（thiabendazolyl）butane（L1） or 1,6-bis（thiabendazolyl）hexane（L2） afforded two coordination polymers [Cd2（L1）（bta）·2H2O]n（1） and [Cd2（L2）2（H2bta）2]n（2）. Complex 1 holds a rare 3D binodal（4,6）-connected framework with fsh topology. Complex 2 features an infinite meandering chain structure, which is further extended via O–H···O hydrogen bonding into a 3D supramolecular network. The thermal and fluorescence proprieties of the two complexes were investigated.展开更多
基金Project supported by the Natural Science Foundation-steel and Iron Foundation of Hebei Province(B2015209299 and E2016209304)
文摘The hydrothermal reactions of Cd（OAc）2·2H2O with 1,2,4,5-benzenetetracarboxylic acid（H4bta） and 1,4-bis（thiabendazolyl）butane（L1） or 1,6-bis（thiabendazolyl）hexane（L2） afforded two coordination polymers [Cd2（L1）（bta）·2H2O]n（1） and [Cd2（L2）2（H2bta）2]n（2）. Complex 1 holds a rare 3D binodal（4,6）-connected framework with fsh topology. Complex 2 features an infinite meandering chain structure, which is further extended via O–H···O hydrogen bonding into a 3D supramolecular network. The thermal and fluorescence proprieties of the two complexes were investigated.
