The hydrothermal reaction of ZnO, H3PO4(85%), (H2NCH2CH2)2NH and H2pydc results in the formation of a discrete mononuclear zinc(II) complex Zn(Hpydc)2(H2O). It crystallizes in monoclinic space group C2/c with a = 17.9...The hydrothermal reaction of ZnO, H3PO4(85%), (H2NCH2CH2)2NH and H2pydc results in the formation of a discrete mononuclear zinc(II) complex Zn(Hpydc)2(H2O). It crystallizes in monoclinic space group C2/c with a = 17.9947(8), b = 7.1875(3), c = 12.5895(4) , b = 110.802(2), V = 1522.14(10) 3, Z = 4, Mr = 415.61, (C14H10N2O9Zn), Dc = 1.814g/cm3, = 16.71cm-1, F(000) = 840, R = 0.0505, wR = 0.1144. Each zinc(II) is coordinated to two nitrogen and three oxygen atoms of which two nitrogen and two oxygen atoms are from two pydc ligands, and one oxygen atom from the coordinated water molecule to form an irregular polyhedral geometry. The complex is linked further into a three-dimensional structure through the weak interactions of hydrogen bonds between the two oxygen atoms. IR spectrum of the complex is also discussed.展开更多
The mononuclear complex [Ag(C6H6NCl)2](ClO() has been prepared and structurally analyzed by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group C2/c with unit cell paramete...The mononuclear complex [Ag(C6H6NCl)2](ClO() has been prepared and structurally analyzed by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group C2/c with unit cell parameters: a=15.5314(2), b=8.0247(8), c=15.3701(2)?.β=118.832(2)°, V=1678.2(3)?3, Z=4, Mr=462.46, Dc=1.830Mg/m3, F(000)=912, μ(MoKα) = 1.694cm-1. The final R and wR are 0.0472 and 0.1272 for 1484 observed reflections with I≥3σ(I). The Ag atom is coordinated by two nitrogen atoms of 4-chloromethyl-pyridine in a linear coordination geometry. Each molecule is further linked by the weak interaction between the Cl and Ag atoms to form a one-dimensional chain structure with Ag－Cl distance of 3.240?.展开更多
基金the National Natural Science Foundation of China the Natural Science Foundation of Fujian Provincea key project from the Chinese Academic of Sciences.
文摘The hydrothermal reaction of ZnO, H3PO4(85%), (H2NCH2CH2)2NH and H2pydc results in the formation of a discrete mononuclear zinc(II) complex Zn(Hpydc)2(H2O). It crystallizes in monoclinic space group C2/c with a = 17.9947(8), b = 7.1875(3), c = 12.5895(4) , b = 110.802(2), V = 1522.14(10) 3, Z = 4, Mr = 415.61, (C14H10N2O9Zn), Dc = 1.814g/cm3, = 16.71cm-1, F(000) = 840, R = 0.0505, wR = 0.1144. Each zinc(II) is coordinated to two nitrogen and three oxygen atoms of which two nitrogen and two oxygen atoms are from two pydc ligands, and one oxygen atom from the coordinated water molecule to form an irregular polyhedral geometry. The complex is linked further into a three-dimensional structure through the weak interactions of hydrogen bonds between the two oxygen atoms. IR spectrum of the complex is also discussed.
文摘The mononuclear complex [Ag(C6H6NCl)2](ClO() has been prepared and structurally analyzed by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group C2/c with unit cell parameters: a=15.5314(2), b=8.0247(8), c=15.3701(2)?.β=118.832(2)°, V=1678.2(3)?3, Z=4, Mr=462.46, Dc=1.830Mg/m3, F(000)=912, μ(MoKα) = 1.694cm-1. The final R and wR are 0.0472 and 0.1272 for 1484 observed reflections with I≥3σ(I). The Ag atom is coordinated by two nitrogen atoms of 4-chloromethyl-pyridine in a linear coordination geometry. Each molecule is further linked by the weak interaction between the Cl and Ag atoms to form a one-dimensional chain structure with Ag－Cl distance of 3.240?.
