采用铜模吸铸法在TiNiCuSn合金系中添加难熔金属Nb,制备出了d3 mm Ti60Cu14Ni12Sn4Nb10棒状多相复合材料。对该合金的显微组织特征和相组成进行了分析,并对其室温压缩性能进行了测试。研究结果表明,Ti60Cu14Ni12Sn4Nb10的显微组织主要由...采用铜模吸铸法在TiNiCuSn合金系中添加难熔金属Nb,制备出了d3 mm Ti60Cu14Ni12Sn4Nb10棒状多相复合材料。对该合金的显微组织特征和相组成进行了分析,并对其室温压缩性能进行了测试。研究结果表明,Ti60Cu14Ni12Sn4Nb10的显微组织主要由β-Ti枝晶相、纳米晶化相和少量非晶相组成。该合金在室温下表现出较好的综合力学性能,其抗压断裂强度可达1.71 GPa,断裂应变约为17.7%,弹性模量为116 GPa。合金的断口分析结果表明,由于产生了塑性枝晶相,因此该合金具有较高塑性。展开更多
The effects of crystallization on the corrosion resistance of a Cu52.5Ti30Zr11.5Ni6 bulk amorphous alloy in 1 mol/L HCl, and 6 mol/L NaOH solutions were studied. The amorphous alloy was identified by differential ther...The effects of crystallization on the corrosion resistance of a Cu52.5Ti30Zr11.5Ni6 bulk amorphous alloy in 1 mol/L HCl, and 6 mol/L NaOH solutions were studied. The amorphous alloy was identified by differential thermal analysis(DSC) and by X-ray diffraction(XRD). The partially and fully crystallized alloys were prepared by controlling the annealing temperatures at 738 and 873 K for 1 and 12 min, respectively, and the corrosion resistances of those annealed alloys were compared with that of the amorphous alloy by immersion test and potentiodynamic measurements in 1 mol/L HCl and 6 mol/L NaOH solutions. The results show that the partially crystallized alloy exhibits high corrosion resistance, whereas full crystallization results in deteriorated corrosion resistance compared with that of the as-cast amorphous alloy.展开更多
Two amorphous ribbons with the compositions of Al88Ni6La6 and Al86Ni6La6Cu2 were made using the melt-spun method,and their thermal response and electrochemical behavior were studied comparatively.Differential scanning...Two amorphous ribbons with the compositions of Al88Ni6La6 and Al86Ni6La6Cu2 were made using the melt-spun method,and their thermal response and electrochemical behavior were studied comparatively.Differential scanning calorimetry（DSC）and electrochemical polarization measurements indicated that Al86Ni6La6Cu2 exhibited slightly higher crystallization temperature（Tx）,lower melting point（Tl）and better corrosion resistance in 0.01 mol·L-1 NaCl alkaline solution.These results demonstrated that Cu（2%）addition could slightly promote the glass forming ability,but it could greatly improve the corrosion resistance of Al88Ni6La6 alloy in 0.01 mol·L-1 NaCl alkaline solution.展开更多
The diffusion bonding of γ-TiAl alloy to Ti-6Al-4V alloy at different temperatures ranging from 1 073 to 1 173 K under an applied stress of 100 MPa for 2 h was studied. The observation of the microstructure reveals t...The diffusion bonding of γ-TiAl alloy to Ti-6Al-4V alloy at different temperatures ranging from 1 073 to 1 173 K under an applied stress of 100 MPa for 2 h was studied. The observation of the microstructure reveals that sound joints between the γ-TiAl alloy and the Ti-alloy without any pores or cracks can be achieved through diffusion bonding at temperatures over 1 073 K under the applied stress of 100 MPa for 2 h. The bond is composed of two zones, and its width increases with the increase of bonding temperature. The EDS chemical composition profiles indicate that there is a diffusion flux of Al atoms from γ-TiAl alloy towards the Ti alloy and of Ti atoms in the opposite direction. The three point-bending of the joints bonded under different conditions was tested and the fracture mode was analyzed by SEM observation.展开更多
文摘采用铜模吸铸法在TiNiCuSn合金系中添加难熔金属Nb,制备出了d3 mm Ti60Cu14Ni12Sn4Nb10棒状多相复合材料。对该合金的显微组织特征和相组成进行了分析,并对其室温压缩性能进行了测试。研究结果表明,Ti60Cu14Ni12Sn4Nb10的显微组织主要由β-Ti枝晶相、纳米晶化相和少量非晶相组成。该合金在室温下表现出较好的综合力学性能,其抗压断裂强度可达1.71 GPa,断裂应变约为17.7%,弹性模量为116 GPa。合金的断口分析结果表明,由于产生了塑性枝晶相,因此该合金具有较高塑性。
基金Project(50371072) supported by the National Natural Science Foundation of ChinaProject(05FJ4048) supported by the Provincial Science and Technology Department Foundation of Hunan, China
文摘The effects of crystallization on the corrosion resistance of a Cu52.5Ti30Zr11.5Ni6 bulk amorphous alloy in 1 mol/L HCl, and 6 mol/L NaOH solutions were studied. The amorphous alloy was identified by differential thermal analysis(DSC) and by X-ray diffraction(XRD). The partially and fully crystallized alloys were prepared by controlling the annealing temperatures at 738 and 873 K for 1 and 12 min, respectively, and the corrosion resistances of those annealed alloys were compared with that of the amorphous alloy by immersion test and potentiodynamic measurements in 1 mol/L HCl and 6 mol/L NaOH solutions. The results show that the partially crystallized alloy exhibits high corrosion resistance, whereas full crystallization results in deteriorated corrosion resistance compared with that of the as-cast amorphous alloy.
基金Project supported by the National Natural Science Foundation of China(50371072)
文摘Two amorphous ribbons with the compositions of Al88Ni6La6 and Al86Ni6La6Cu2 were made using the melt-spun method,and their thermal response and electrochemical behavior were studied comparatively.Differential scanning calorimetry（DSC）and electrochemical polarization measurements indicated that Al86Ni6La6Cu2 exhibited slightly higher crystallization temperature（Tx）,lower melting point（Tl）and better corrosion resistance in 0.01 mol·L-1 NaCl alkaline solution.These results demonstrated that Cu（2%）addition could slightly promote the glass forming ability,but it could greatly improve the corrosion resistance of Al88Ni6La6 alloy in 0.01 mol·L-1 NaCl alkaline solution.
基金Project(50371072) supported by the National Natural Science Foundation of China
文摘The diffusion bonding of γ-TiAl alloy to Ti-6Al-4V alloy at different temperatures ranging from 1 073 to 1 173 K under an applied stress of 100 MPa for 2 h was studied. The observation of the microstructure reveals that sound joints between the γ-TiAl alloy and the Ti-alloy without any pores or cracks can be achieved through diffusion bonding at temperatures over 1 073 K under the applied stress of 100 MPa for 2 h. The bond is composed of two zones, and its width increases with the increase of bonding temperature. The EDS chemical composition profiles indicate that there is a diffusion flux of Al atoms from γ-TiAl alloy towards the Ti alloy and of Ti atoms in the opposite direction. The three point-bending of the joints bonded under different conditions was tested and the fracture mode was analyzed by SEM observation.
