The complex with the formula [CeFe(CN)(6)(H2O)(3)]. 2H(2)O was synthesized and structurally characterized. It crystallizes in hexagonal, space group P3, a = 0.75320(10) nm, b = 0.75320(10) nm, c = 1.4374(3) nm, gamma ...The complex with the formula [CeFe(CN)(6)(H2O)(3)]. 2H(2)O was synthesized and structurally characterized. It crystallizes in hexagonal, space group P3, a = 0.75320(10) nm, b = 0.75320(10) nm, c = 1.4374(3) nm, gamma = 120 degrees, V = 0.7062(2) nm(3), Z = 3, Be = 3.048 Mg .m(-3), F(000) = 606, mu = 6.346 mm(-1), T = 293(2) K, R-1 = 0.0169, wR(2) = 0.0459. The structure is a three-dimensional network containing open channels formed by the nine-coordinated CeN6(H2O)(3) groups and octahedral FeC6 groups through the cyanide linkages. Magnetic susceptibility measurements in the temperature range of 5.1 similar to 300 It show an antiferromagnetic interaction between the Ce3+ and Fe3+ ions.展开更多
文摘The complex with the formula [CeFe(CN)(6)(H2O)(3)]. 2H(2)O was synthesized and structurally characterized. It crystallizes in hexagonal, space group P3, a = 0.75320(10) nm, b = 0.75320(10) nm, c = 1.4374(3) nm, gamma = 120 degrees, V = 0.7062(2) nm(3), Z = 3, Be = 3.048 Mg .m(-3), F(000) = 606, mu = 6.346 mm(-1), T = 293(2) K, R-1 = 0.0169, wR(2) = 0.0459. The structure is a three-dimensional network containing open channels formed by the nine-coordinated CeN6(H2O)(3) groups and octahedral FeC6 groups through the cyanide linkages. Magnetic susceptibility measurements in the temperature range of 5.1 similar to 300 It show an antiferromagnetic interaction between the Ce3+ and Fe3+ ions.
