研究了两种钙含量相同、锌含量（质量分数）不同的镁合金（Mg-1.0％Ca-0.3％Zn和Mg-1.0％Ca-1.0％Zn）在模拟体液（Simulated body fluid,SBF）中的腐蚀行为.通过三电极体系动电位法、析氢法、pH计和扫描电子显微镜对合金在SBF中的极化...研究了两种钙含量相同、锌含量（质量分数）不同的镁合金（Mg-1.0％Ca-0.3％Zn和Mg-1.0％Ca-1.0％Zn）在模拟体液（Simulated body fluid,SBF）中的腐蚀行为.通过三电极体系动电位法、析氢法、pH计和扫描电子显微镜对合金在SBF中的极化曲线、浸泡过程中析出氢气量、SBF的pH值变化以及浸泡后的合金形貌进行分析和研究.结果表明：两种合金的耐腐蚀性均好于纯镁,其中合金Mg-1.0％Ca-1.0％Zn较合金Mg-1.0％Ca-0.3％Zn在SBF中极化阻力大,析出氢气量减少,在1～48 h内SBF溶液的pH值增加较快,SBF溶液的碱化较快;浸泡后合金Mg-1.0％Ca-1.0％Zn表面较平整,合金的耐腐蚀性较好,腐蚀速率能基本满足作为体内植入生物材料的要求,且在SBF中日离子溶出量不超过人体耐受量的前提下,其体内植入物制品表面积上限可达179 cm2,具有较大的实用性.展开更多
研究了Mg-1.0Ca-0.3Zn合金在银离子剂量为1.5×1017cm-2注入条件下,在模拟体液(simulated body flmd,SBF)中的耐腐蚀性.通过纳米压痕和三电极体系法对合金的表面硬度和弹性模量、在SBF中的极化曲线测定表明:经过银离子注入后,合金...研究了Mg-1.0Ca-0.3Zn合金在银离子剂量为1.5×1017cm-2注入条件下,在模拟体液(simulated body flmd,SBF)中的耐腐蚀性.通过纳米压痕和三电极体系法对合金的表面硬度和弹性模量、在SBF中的极化曲线测定表明:经过银离子注入后,合金的表面硬度和pH值逐渐增加,加快了SBF溶液的碱化.Abstract：The corrosion resistance of Ag ion implanted with dose of 1.5×1017 cm-2 for Mg-1.0 Ca-0.3 Zn magnesium alloy in the simulated body fluid was investigated. The surface hardness and elastic modulus of the alloy and the polarization curve in the SBF were obtained by Nano Snick and three electrode system, respectively. The results indicate that the hardness and the elastic modulus are improved obviously after the implantation of Ag ions, the surface hardness reaches the maximum at a depth of 250 nm below the alloy surface. Meanwhile, the polarization resistance is strengthened, and consequently the corrosion resistance of the alloy is improved. Moreover, the pH value of the SBF within 48 h increases gradually and the alkalization of the SBF is accelerated.展开更多
文摘研究了两种钙含量相同、锌含量（质量分数）不同的镁合金（Mg-1.0％Ca-0.3％Zn和Mg-1.0％Ca-1.0％Zn）在模拟体液（Simulated body fluid,SBF）中的腐蚀行为.通过三电极体系动电位法、析氢法、pH计和扫描电子显微镜对合金在SBF中的极化曲线、浸泡过程中析出氢气量、SBF的pH值变化以及浸泡后的合金形貌进行分析和研究.结果表明：两种合金的耐腐蚀性均好于纯镁,其中合金Mg-1.0％Ca-1.0％Zn较合金Mg-1.0％Ca-0.3％Zn在SBF中极化阻力大,析出氢气量减少,在1～48 h内SBF溶液的pH值增加较快,SBF溶液的碱化较快;浸泡后合金Mg-1.0％Ca-1.0％Zn表面较平整,合金的耐腐蚀性较好,腐蚀速率能基本满足作为体内植入生物材料的要求,且在SBF中日离子溶出量不超过人体耐受量的前提下,其体内植入物制品表面积上限可达179 cm2,具有较大的实用性.
基金Tianjin Science and Technology Project(07ZCKFSF01100)
文摘研究了Mg-1.0Ca-0.3Zn合金在银离子剂量为1.5×1017cm-2注入条件下,在模拟体液(simulated body flmd,SBF)中的耐腐蚀性.通过纳米压痕和三电极体系法对合金的表面硬度和弹性模量、在SBF中的极化曲线测定表明:经过银离子注入后,合金的表面硬度和pH值逐渐增加,加快了SBF溶液的碱化.Abstract：The corrosion resistance of Ag ion implanted with dose of 1.5×1017 cm-2 for Mg-1.0 Ca-0.3 Zn magnesium alloy in the simulated body fluid was investigated. The surface hardness and elastic modulus of the alloy and the polarization curve in the SBF were obtained by Nano Snick and three electrode system, respectively. The results indicate that the hardness and the elastic modulus are improved obviously after the implantation of Ag ions, the surface hardness reaches the maximum at a depth of 250 nm below the alloy surface. Meanwhile, the polarization resistance is strengthened, and consequently the corrosion resistance of the alloy is improved. Moreover, the pH value of the SBF within 48 h increases gradually and the alkalization of the SBF is accelerated.
