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垂直磁场作用下水平微电极表面气泡生长特性实验研究 被引量:6
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作者 詹水清 黄雨捷 +3 位作者 王军锋 江明镅 张伟 王贞涛 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2021年第1期249-258,共10页
为探究不同电磁场产生的微观磁对流对水平微电极表面单个气泡生长行为的影响,建立恒定电流的电解水制氢实验系统。应用高速摄像可视化技术对电极表面气泡生长过程进行观察,结合OpenCV-Python自定义程序对气泡生长行为特征参数进行提取... 为探究不同电磁场产生的微观磁对流对水平微电极表面单个气泡生长行为的影响,建立恒定电流的电解水制氢实验系统。应用高速摄像可视化技术对电极表面气泡生长过程进行观察,结合OpenCV-Python自定义程序对气泡生长行为特征参数进行提取和分析。研究结果表明:在气泡生长周期内,气泡直径逐渐增大,气泡生长速率先增大后减小,外加磁场对气泡生长速率几乎没有影响,气泡生长速率随电解电流密度的增大而增大。与低电解电流密度工况相比,高电解电流密度下的气泡脱离直径明显偏大,气泡生长时间明显延长,工作电极电势明显偏高。随着磁感应强度增大,低电解电流密度和高电解电流密度条件下的气泡脱离直径、气泡生长时间和工作电极电势均呈现相反的变化趋势,高强度磁场或高电解电流密度作用使磁场的影响效果减弱。不同电解电流密度和磁感应强度下工作电极电势与气泡接触直径的变化规律类似,揭示出工作电极电势变化与电极表面气泡生长行为密切相关。 展开更多
关键词 垂直磁场 气泡生长 脱离直径 生长时间 电极电势
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Improved CFD modeling of full dissolution of alumina particles in aluminum electrolysis cells considering agglomerate formation 被引量:2
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作者 Shui-qing ZHAN Ming-mei JIANG +1 位作者 Jun-feng WANG Jian-hong YANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第11期3579-3590,共12页
The full alumina dissolution process in aluminum electrolysis cells was investigated using an improved computational fluid dynamics(CFD)model based on the previous researches by consideration of agglomerate formation.... The full alumina dissolution process in aluminum electrolysis cells was investigated using an improved computational fluid dynamics(CFD)model based on the previous researches by consideration of agglomerate formation.The results show that the total mass of alumina agglomerate and its maximum size are mainly dependent on the feeding amount and increase with increasing it.Higher superheat can effectively inhibit the agglomerate formation and thus promote the full alumina dissolution behavior.The full alumina dissolution process mainly includes a fast stage and a slow stage,with an average dissolution rate of 17.24 kg/min and 1.53 kg/min,respectively.About 50%(mass percentage)of the total alumina particles,almost all of which are the well-dispersed alumina fine grains,dissolve within the fast dissolution stage of about 10 s.The maximum values of the average dissolution rate and final percentage of the cumulative dissolved alumina mass are obtained with a feeding amount of 1.8 kg for a superheat of 12℃.The formation of the alumina agglomerates and slow dissolution characteristics play a dominant role in the full dissolution of alumina particles. 展开更多
关键词 aluminum electrolysis alumina dissolution agglomerate formation theoretical modeling CFD modeling
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