Additives and iodine(I_2) are used to modify the binary room temperature ionic liquid(RTIL) electrolyte to enhance the photovoltaic performance of dye-sensitized solar cells(DSSCs). The short-circuit current density(J...Additives and iodine(I_2) are used to modify the binary room temperature ionic liquid(RTIL) electrolyte to enhance the photovoltaic performance of dye-sensitized solar cells(DSSCs). The short-circuit current density(JSC) of 17.89 m A/ cm2, open circuit voltage(VOC) of 0.71 V and fill factor(FF) of 0.50 are achieved in the optimal device. An average photoelectric conversion efficiency(PCE) of 6.35% is achieved by optimization, which is over two times larger than that of the parent device before optimization(2.06%), while the maximum PCE can reach up to 6.63%.展开更多
The photovoltaic performance of dye-sensitized solar cells （DSSCs） is enhanced by modifying the binary room tem- perature ionic liquid （RTIL） electrolyte with additives and iodine. The average photoelectric conver...The photovoltaic performance of dye-sensitized solar cells （DSSCs） is enhanced by modifying the binary room tem- perature ionic liquid （RTIL） electrolyte with additives and iodine. The average photoelectric conversion efficiency （PCE） of 6.39% is achieved. Through electrochemical impedance spectroscopy （EIS）, cyclic voltammetry scans and incident photon-to-current conversion efficiency （1PCE） data, the working principles are analyzed. The enhancement is mainly attributed to the improvement of short circuit current which is caused by the reduction of overall internal resistance of the devices. Durability tests are measured at room temperature, and the long-term stability performance can be maintained.展开更多
基金supported by the National Basic Research Program of China(No.2015CB932200)the National Natural Science Foundation of China(No.61474064)+2 种基金the Innovation Team Development Plan of the Ministry of Education of China(No.IRT1148)the Priority Academic Program Development of Jiangsu Higher Education Institutions(No.YX03001)the Nanjing University of Posts and Telecommunications(Nos.NY212076 and NY212050)
文摘Additives and iodine(I_2) are used to modify the binary room temperature ionic liquid(RTIL) electrolyte to enhance the photovoltaic performance of dye-sensitized solar cells(DSSCs). The short-circuit current density(JSC) of 17.89 m A/ cm2, open circuit voltage(VOC) of 0.71 V and fill factor(FF) of 0.50 are achieved in the optimal device. An average photoelectric conversion efficiency(PCE) of 6.35% is achieved by optimization, which is over two times larger than that of the parent device before optimization(2.06%), while the maximum PCE can reach up to 6.63%.
基金supported by the National Natural Science Foundation of China(No.61474064)
文摘The photovoltaic performance of dye-sensitized solar cells （DSSCs） is enhanced by modifying the binary room tem- perature ionic liquid （RTIL） electrolyte with additives and iodine. The average photoelectric conversion efficiency （PCE） of 6.39% is achieved. Through electrochemical impedance spectroscopy （EIS）, cyclic voltammetry scans and incident photon-to-current conversion efficiency （1PCE） data, the working principles are analyzed. The enhancement is mainly attributed to the improvement of short circuit current which is caused by the reduction of overall internal resistance of the devices. Durability tests are measured at room temperature, and the long-term stability performance can be maintained.
