气相色谱法研究配合物的热稳定性(ⅩⅤ)-表面配合物热分解动力学方法

研究了表面配合物的热分解动力学问题,计算了若干MgO的表面Madelung常数,并把H_(2)C_(3)O_(4)-MgO体系的热分解动力学问题转化为均匀表面的迭加问题处理。对于更复杂的体系,基于表面能量的不均匀性,提出了动力学方程。

MSSBAUER SPECTRA OF K_4[Fe(CN)_6]·3H_2O IN MAGNETIC FIELD

The Mssbauer spectra of K4[Fe（CN）6]·3H2O in external magnetic field at room temperature have been obtained using a single line source of 'Co/Pd. The experiment was carried out with an absorber of K4[Fe（CN）6]·3H2O （A. R. grade） in external magnetic field and the γ-ray