Hydrothermal reactions of Bi2O3 with pyridine-2,6-dicarboxylic acid (2,6-H2pdc) and trimesic acid (H3btc)/pyromellitic acid (H4pyr) lead to two bismuth-organic frameworks, namely, [Bi(2,6-pdc)(H2btc)(H2O)2...Hydrothermal reactions of Bi2O3 with pyridine-2,6-dicarboxylic acid (2,6-H2pdc) and trimesic acid (H3btc)/pyromellitic acid (H4pyr) lead to two bismuth-organic frameworks, namely, [Bi(2,6-pdc)(H2btc)(H2O)2]n (1) and [Bi2(2,6-pdc)2(H2pyr)(H2O)2]n (2). Compound 1 crystallizes in the space group P21/c. The dimeric {Bi2} units are linked by 2,6-pdc2? ligands to form 1D chains; Compound 2 exhibits a 2D layered structure with 44 network topology by using dimeric {Bi2} as secondary building units (SBUs). The chains and layers in 1 and 2 are further arranged into 3D supramolecular structures via hydrogen bonding interactions. The compounds emit blue luminescence. Furthermore, the PXRD, TGA, UV-visible and IR spectra were also studied. Compounds 1, 2 represent good examples of using mixed-ligand approach to construct diversity of luminescent bismuth-organic frameworks.展开更多
基金Supported by the NNSF of China(21471130)the research fund for the doctoral program of higher education of China(Grant 201244200120007)
文摘Hydrothermal reactions of Bi2O3 with pyridine-2,6-dicarboxylic acid (2,6-H2pdc) and trimesic acid (H3btc)/pyromellitic acid (H4pyr) lead to two bismuth-organic frameworks, namely, [Bi(2,6-pdc)(H2btc)(H2O)2]n (1) and [Bi2(2,6-pdc)2(H2pyr)(H2O)2]n (2). Compound 1 crystallizes in the space group P21/c. The dimeric {Bi2} units are linked by 2,6-pdc2? ligands to form 1D chains; Compound 2 exhibits a 2D layered structure with 44 network topology by using dimeric {Bi2} as secondary building units (SBUs). The chains and layers in 1 and 2 are further arranged into 3D supramolecular structures via hydrogen bonding interactions. The compounds emit blue luminescence. Furthermore, the PXRD, TGA, UV-visible and IR spectra were also studied. Compounds 1, 2 represent good examples of using mixed-ligand approach to construct diversity of luminescent bismuth-organic frameworks.