The NaYF4:Yb,Er nanocrystals were synthesized via the thermal decomposition ot metal oleate precursors, lhe nanocrys- tals in hexagonal structure were highly uniform and in size of 25 nm. The bright upconversion lumi...The NaYF4:Yb,Er nanocrystals were synthesized via the thermal decomposition ot metal oleate precursors, lhe nanocrys- tals in hexagonal structure were highly uniform and in size of 25 nm. The bright upconversion luminescence was observed under the excitation of 980 nm laser and the upeonversion emission spectra were investigated at different pump powers. The emission intensity ratio of red light to green light linearly increased with pump power increasing. This result indicated that there existed a large threshold power of saturation pump for the first excitation state in NaYFa:Yb,Er nanocrystals comparing to that in bulk material.展开更多
基金Project supported by Fund for Fostering Talents in Basic Science of the National Natural Science Foundation of China(J1103207)the National Natural Science Foundation of China(11274288,21002097)+1 种基金the National Basic Research Program of China(2011CB932801,2012CB933702)Ministry of Education of China(20123402110034)
文摘The NaYF4:Yb,Er nanocrystals were synthesized via the thermal decomposition ot metal oleate precursors, lhe nanocrys- tals in hexagonal structure were highly uniform and in size of 25 nm. The bright upconversion luminescence was observed under the excitation of 980 nm laser and the upeonversion emission spectra were investigated at different pump powers. The emission intensity ratio of red light to green light linearly increased with pump power increasing. This result indicated that there existed a large threshold power of saturation pump for the first excitation state in NaYFa:Yb,Er nanocrystals comparing to that in bulk material.