Using angle-resolved photoemission spectroscopy,we study electronic structures of a Kagome metal YCr6Ge6.Band dispersions along kz direction are significant,suggesting a remarkable interlayer coupling between neighbor...Using angle-resolved photoemission spectroscopy,we study electronic structures of a Kagome metal YCr6Ge6.Band dispersions along kz direction are significant,suggesting a remarkable interlayer coupling between neighboring Kagome planes.Comparing ARPES data with first-principles calculations,we find a moderate electron correlation in this material,since band calculations must be compressed in the energy scale to reach an excellent agreement between experimental data and theoretical calculations.Moreover,as indicated by band calculations,there is a flat band in the vicinity of the Fermi level at the Г–M–K plane in the momentum space,which could be responsible for the unusual transport behavior in YCr6Ge6.展开更多
As a special order of electronic correlation induced by spatial modulation, the charge density wave(CDW) phenomena in condensed matters attract enormous research interests. Here, using scanning-tunneling microscopy in...As a special order of electronic correlation induced by spatial modulation, the charge density wave(CDW) phenomena in condensed matters attract enormous research interests. Here, using scanning-tunneling microscopy in various temperatures, we discover a hidden incommensurate stripe-like CDW order besides the(■) CDW phase at low-temperature of 4 K in the epitaxial monolayer 1T-VSe_(2) film. Combining the variable-temperature angle-resolved photoemission spectroscopic(ARPES) measurements, we discover a two-step transition of an anisotropic CDW gap structure that consists of two parts △_(1) and△_(2). The gap part ?1 that closes around ~ 150 K is accompanied with the vanish of the(√7×√3) CDW phase. While another momentum-dependent gap part △_(2) can survive up to ~ 340 K, and is suggested to the result of the incommensurate CDW phase. This two-step transition with anisotropic gap opening and the resulted evolution in ARPES spectra are corroborated by our theoretical calculation based on a phenomenological form for the self-energy containing a two-gap structure △_(1) +△_(2), which suggests different forming mechanisms between the(√7×√3) and the incommensurate CDW phases. Our findings provide significant information and deep understandings on the CDW phases in monolayer 1T-VSe_(2) film as a two-dimensional(2D) material.展开更多
Monolayer MnTe_(2)stabilized as 1 T structure has been theoretically predicted to be a two-dimensional(2 D)ferromagnetic metal and can be tuned via strain engineering.There is no naturally van der Waals(vdW)layered Mn...Monolayer MnTe_(2)stabilized as 1 T structure has been theoretically predicted to be a two-dimensional(2 D)ferromagnetic metal and can be tuned via strain engineering.There is no naturally van der Waals(vdW)layered MnTe_(2)bulk,leaving mechanical exfoliation impossible to prepare monolayer MnTe_(2).Herein,by means of molecular beam epitaxy(MBE),we successfully prepared monolayer hexagonal MnTe_(2)on Si(111)under Te rich condition.Sharp reflection high-energy electron diffraction(RHEED)and low-energy electron diffraction(LEED)patterns suggest the monolayer is atomically flat without surface reconstruction.The valence state of Mn^(4+)and the atom ratio of([Te]:[Mn])further confirm the MnTe_(2)compound.Scanning tunneling spectroscopy(STS)shows the hexagonal MnTe_(2)monolayer is a semiconductor with a large bandgap of~2.78 eV.The valence-band maximum(VBM)locates at theΓpoint,as illustrated by angle-resolved photoemission spectroscopy(ARPES),below which three hole-type bands with parabolic dispersion can be identified.The successful synthesis of monolayer MnTe_(2)film provides a new platform to investigate the 2D magnetism.展开更多
Two-dimensional honeycomb crystals have inspired intense research interest for their novel properties and great potential in electronics and optoelectronics. Here, through molecular beam epitaxy on SrTiO_3(001), we re...Two-dimensional honeycomb crystals have inspired intense research interest for their novel properties and great potential in electronics and optoelectronics. Here, through molecular beam epitaxy on SrTiO_3(001), we report successful epitaxial growth of metal-rich chalcogenide Fe_(2)Te, a honeycomb-structured film that has no direct bulk analogue, under Te-limited growth conditions. The structural morphology and electronic properties of Fe_(2)Te are explored with scanning tunneling microscopy and angle resolved photoemission spectroscopy, which reveal electronic bands cross the Fermi level and nearly flat bands. Moreover, we find a weak interfacial interaction between Fe_(2)Te and the underlying substrates, paving a newly developed alternative avenue for honeycomb-based electronic devices.展开更多
The Weyl semimetal has emerged as a new topologically nontrivial phase of matter,hosting low-energy excitations of massless Weyl fermions.Here,we present a comprehensive study of a type-ⅡWeyl semimetal WP2.Transport ...The Weyl semimetal has emerged as a new topologically nontrivial phase of matter,hosting low-energy excitations of massless Weyl fermions.Here,we present a comprehensive study of a type-ⅡWeyl semimetal WP2.Transport studies show a butterfly-like magnetoresistance at low temperature,reflecting the anisotropy of the electron Fermi surfaces.This four-lobed feature gradually evolves into a two-lobed variant with an increase in temperature,mainly due to the reduced relative contribution of electron Fermi surfaces compared to hole Fermi surfaces for magnetoresistance.Moreover,an angle-dependent Berry phase is also discovered,based on quantum oscillations,which is ascribed to the effective manipulation of extremal Fermi orbits by the magnetic field to feel nearby topological singularities in the momentum space.The revealed topological character and anisotropic Fermi surfaces of the WP2 substantially enrich the physical properties of Weyl semimetals,and show great promises in terms of potential topological electronic and Fermitronic device applications.展开更多
The band structures of two-monolayer Bi(110) films on black phosphorus substrates are studied using angleresolved photoemission spectroscopy. Within the band gap of bulk black phosphorus, the electronic states near ...The band structures of two-monolayer Bi(110) films on black phosphorus substrates are studied using angleresolved photoemission spectroscopy. Within the band gap of bulk black phosphorus, the electronic states near the Fermi level are dominated by the Bi(110) film. The band dispersions revealed by our data suggest that the orientation of the Bi(110) film is aligned with the black phosphorus substrate. The electronic structures of the Bi(110) film strongly deviate from the band calculations of the free-standing Bi(110) film, suggesting that the substrate can significantly affect the electronic states in the Bi(110) film. Our data show that there are no non-trivial electronic states in Bi(110) films grown on black phosphorus substrates.展开更多
基金Supported by the National Key R&D Program of China(Grant Nos.2017YFA0402901,2016YFA0401004 and 2016YFA0300404)the National Natural Science Foundation of China(Grant Nos.11674296,11974354 and U1432138)+3 种基金the Key Research Program of the Chinese Academy of Sciences(Grant No.XDPB01)the Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(Grant No.2018CXFX002)the Collaborative Innovation Program of Hefei Science Center,CAS(Grant No.2019HSC-CIP007)the High Magnetic Field Laboratory of Anhui Province.
文摘Using angle-resolved photoemission spectroscopy,we study electronic structures of a Kagome metal YCr6Ge6.Band dispersions along kz direction are significant,suggesting a remarkable interlayer coupling between neighboring Kagome planes.Comparing ARPES data with first-principles calculations,we find a moderate electron correlation in this material,since band calculations must be compressed in the energy scale to reach an excellent agreement between experimental data and theoretical calculations.Moreover,as indicated by band calculations,there is a flat band in the vicinity of the Fermi level at the Г–M–K plane in the momentum space,which could be responsible for the unusual transport behavior in YCr6Ge6.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 92165205, 11790311, 12004172, 11774152, 11604366, and 11634007)the National Key Research and Development Program of China (Grant Nos. 2018YFA0306800 and 2016YFA0300401)+1 种基金the Program of High-Level Entrepreneurial and Innovative Talents Introduction of Jiangsu Province, the Jiangsu Planned Projects for Postdoctoral Research Funds (Grant No. 2020Z172)the Natural Science Foundation of Jiangsu Province, China (Grant No. BK 20160397)。
文摘As a special order of electronic correlation induced by spatial modulation, the charge density wave(CDW) phenomena in condensed matters attract enormous research interests. Here, using scanning-tunneling microscopy in various temperatures, we discover a hidden incommensurate stripe-like CDW order besides the(■) CDW phase at low-temperature of 4 K in the epitaxial monolayer 1T-VSe_(2) film. Combining the variable-temperature angle-resolved photoemission spectroscopic(ARPES) measurements, we discover a two-step transition of an anisotropic CDW gap structure that consists of two parts △_(1) and△_(2). The gap part ?1 that closes around ~ 150 K is accompanied with the vanish of the(√7×√3) CDW phase. While another momentum-dependent gap part △_(2) can survive up to ~ 340 K, and is suggested to the result of the incommensurate CDW phase. This two-step transition with anisotropic gap opening and the resulted evolution in ARPES spectra are corroborated by our theoretical calculation based on a phenomenological form for the self-energy containing a two-gap structure △_(1) +△_(2), which suggests different forming mechanisms between the(√7×√3) and the incommensurate CDW phases. Our findings provide significant information and deep understandings on the CDW phases in monolayer 1T-VSe_(2) film as a two-dimensional(2D) material.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11604366,11634007,21872099,and 22072102)the National Natural Science Foundation of Jiangsu Province,China(Grant No.BK 20160397)support from the Youth Innovation Promotion Association of Chinese Academy of Sciences(Grant No.2017370)。
文摘Monolayer MnTe_(2)stabilized as 1 T structure has been theoretically predicted to be a two-dimensional(2 D)ferromagnetic metal and can be tuned via strain engineering.There is no naturally van der Waals(vdW)layered MnTe_(2)bulk,leaving mechanical exfoliation impossible to prepare monolayer MnTe_(2).Herein,by means of molecular beam epitaxy(MBE),we successfully prepared monolayer hexagonal MnTe_(2)on Si(111)under Te rich condition.Sharp reflection high-energy electron diffraction(RHEED)and low-energy electron diffraction(LEED)patterns suggest the monolayer is atomically flat without surface reconstruction.The valence state of Mn^(4+)and the atom ratio of([Te]:[Mn])further confirm the MnTe_(2)compound.Scanning tunneling spectroscopy(STS)shows the hexagonal MnTe_(2)monolayer is a semiconductor with a large bandgap of~2.78 eV.The valence-band maximum(VBM)locates at theΓpoint,as illustrated by angle-resolved photoemission spectroscopy(ARPES),below which three hole-type bands with parabolic dispersion can be identified.The successful synthesis of monolayer MnTe_(2)film provides a new platform to investigate the 2D magnetism.
基金Supported by the National Natural Science Foundation of China (Grant Nos. 51788104, 11604366, 11774192, and 11634007)the National Key R&D Program of China (Grant Nos. 2017YFA0304600 and 2018YFA0305603)。
文摘Two-dimensional honeycomb crystals have inspired intense research interest for their novel properties and great potential in electronics and optoelectronics. Here, through molecular beam epitaxy on SrTiO_3(001), we report successful epitaxial growth of metal-rich chalcogenide Fe_(2)Te, a honeycomb-structured film that has no direct bulk analogue, under Te-limited growth conditions. The structural morphology and electronic properties of Fe_(2)Te are explored with scanning tunneling microscopy and angle resolved photoemission spectroscopy, which reveal electronic bands cross the Fermi level and nearly flat bands. Moreover, we find a weak interfacial interaction between Fe_(2)Te and the underlying substrates, paving a newly developed alternative avenue for honeycomb-based electronic devices.
基金Supported by the National Natural Science Foundation of China(Grant Nos.11974324,11804326,U1832151,and 11674296),the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDC07010000)the National Key Research and Development Program of China(Grant No.2017YFA0403600)+4 种基金the Anhui Initiative in Quantum Information Technologies(Grant No.AHY170000)the Hefei Science Center CAS(Grant No.2018HSC-UE014)the Jiangsu Provincial Science Foundation for Youth(Grant No.BK20170821)the National Natural Science Foundation of China for Youth(Grant No.11804160)the Anhui Provincial Natural Science Foundation(Grant No.1708085MF136)。
文摘The Weyl semimetal has emerged as a new topologically nontrivial phase of matter,hosting low-energy excitations of massless Weyl fermions.Here,we present a comprehensive study of a type-ⅡWeyl semimetal WP2.Transport studies show a butterfly-like magnetoresistance at low temperature,reflecting the anisotropy of the electron Fermi surfaces.This four-lobed feature gradually evolves into a two-lobed variant with an increase in temperature,mainly due to the reduced relative contribution of electron Fermi surfaces compared to hole Fermi surfaces for magnetoresistance.Moreover,an angle-dependent Berry phase is also discovered,based on quantum oscillations,which is ascribed to the effective manipulation of extremal Fermi orbits by the magnetic field to feel nearby topological singularities in the momentum space.The revealed topological character and anisotropic Fermi surfaces of the WP2 substantially enrich the physical properties of Weyl semimetals,and show great promises in terms of potential topological electronic and Fermitronic device applications.
基金Supported by National Key R&D Program of China under Grant Nos 2017YFA0402901,2016YFA0401004 and 2016YFB0901600the National Natural Science Foundation of China under Grant Nos 11534010,11404172,U1532136,U1632102,U1632272,11574201,11674296 and 11190022+3 种基金the National Basic Research Program of China under Grant No 2014CB921102the Key Research Program of the Chinese Academy of Sciences under Grant Nos QYZDY-SSW-SLH021 and XDPB01the Interdisciplinary Innovation Team of Chinese Academy of Sciencesthe Initiative Scientific Research Program of Shanghai Jiao Tong University
文摘The band structures of two-monolayer Bi(110) films on black phosphorus substrates are studied using angleresolved photoemission spectroscopy. Within the band gap of bulk black phosphorus, the electronic states near the Fermi level are dominated by the Bi(110) film. The band dispersions revealed by our data suggest that the orientation of the Bi(110) film is aligned with the black phosphorus substrate. The electronic structures of the Bi(110) film strongly deviate from the band calculations of the free-standing Bi(110) film, suggesting that the substrate can significantly affect the electronic states in the Bi(110) film. Our data show that there are no non-trivial electronic states in Bi(110) films grown on black phosphorus substrates.