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卟啉/酞菁光电材料分子电场调控 被引量:1
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作者 穆希皎 买嗣备 +1 位作者 李丛平 曹靖 《中国科学:化学》 CAS CSCD 北大核心 2022年第8期1341-1356,共16页
卟啉/酞菁是一类高度共轭的杂环化合物,如何实现光电性质的精准调控是推动其光电应用的关键.分子电场是分子偶极或者分子晶体中偶极在分子或晶体内部引发的一种局域电场.对分子电场的调变相当于改变了分子或晶体的固有偶极,进而影响材... 卟啉/酞菁是一类高度共轭的杂环化合物,如何实现光电性质的精准调控是推动其光电应用的关键.分子电场是分子偶极或者分子晶体中偶极在分子或晶体内部引发的一种局域电场.对分子电场的调变相当于改变了分子或晶体的固有偶极,进而影响材料的载流子传输及光学性质,因此分子电场优化是调控材料光电性能的一种有效方法.本文阐述了分子偶极与分子电场的关系,综述了卟啉/酞菁分子电场调控其光电性能的研究工作,并介绍了本课题组发展的分子电场有效调控电荷传输行为的研究工作,阐明了分子电场对光电材料电荷分离传输及光学性质调变机制,对新型卟啉/酞菁光电材料理性设计提供了全新的研究思路. 展开更多
关键词 卟啉 酞菁 光电材料 分子电场 光电应用
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TM-pass polarizer based on multilayer graphene polymer waveguide 被引量:1
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作者 蔡可苏 李月娥 +4 位作者 魏文静 穆希皎 马阿宁 王忠 宋丹明 《Optoelectronics Letters》 EI 2018年第3期180-184,共5页
A TM-pass polarizer based on multilayer graphene polymer waveguide is proposed and theoretically analyzed.The mode properties,the extinction ratio,the insertion loss and the bandwidth are also discussed.The results sh... A TM-pass polarizer based on multilayer graphene polymer waveguide is proposed and theoretically analyzed.The mode properties,the extinction ratio,the insertion loss and the bandwidth are also discussed.The results show that a TM-pass polarizer,which only guides the TM mode,can be achieved by multilayer graphene polymer waveguide.With length of 150μm,the proposed polarizer can achieve extinction ratio of 33 dB and insertion loss of 0.5 d B at optical wavelength of 1.55μm.This device has an excellent performance,including large extinction ratio and low insertion loss within the spectral range from 1.45μm to 1.6μm. 展开更多
关键词 TM-pass POLARIZER MULTILAYER GRAPHENE poly-mer waveguide
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Design and analysis of Wedge-enhanced Raman spectroscopy substrate
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作者 马阿宁 魏文静 +4 位作者 彭嗣昌 李月娥 蔡可苏 王忠 穆希皎 《Optoelectronics Letters》 EI 2021年第5期262-265,共4页
Here,a novel Au Wedge-enhanced Raman spectroscopy(WERS)substrate is proposed.The electric field enhancement factor and the effective mode field radius with varying geometry parameters are investigated.The proper excit... Here,a novel Au Wedge-enhanced Raman spectroscopy(WERS)substrate is proposed.The electric field enhancement factor and the effective mode field radius with varying geometry parameters are investigated.The proper excitation wavelength 633 nm is obtained.The practical application of WERS substrate is discussed.The Au WERS not only can provide a continuous extremely highly localized electric field as surface-enhanced Raman scattering(SERS)hotspots,but also can offer 10 orders of magnitude of SERS enhancement factor.The corresponding results reveal that WERS substrate will be widely applied in optics,biology,chemistry and other fields. 展开更多
关键词 Design and analysis of Wedge-enhanced Raman spectroscopy substrate RAMAN
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