The high-pressure diagram of V–N compounds is enriched by proposed seven new stable high-pressure phases.The P-1-VN_4with the armchair N-rich structure may be quenched to ambient conditions.The formed N–N covalent b...The high-pressure diagram of V–N compounds is enriched by proposed seven new stable high-pressure phases.The P-1-VN_4with the armchair N-rich structure may be quenched to ambient conditions.The formed N–N covalent bond plays an important role for the structural stability of N-chain.The charge transfer results in a V–N ionic bond interaction,which further improves the stability of N-chain structure.The P-1-VN_4,P4mnc-VN_8,and Immm-VN_(10)with the outstanding detonation properties have potential application in explosive field.展开更多
Pressure generation to a higher pressure range in a large-volume press(LVP)denotes our ability to explore more functional materials and deeper Earth's interior.Pressure generated by normal tungsten carbide(WC)anvi...Pressure generation to a higher pressure range in a large-volume press(LVP)denotes our ability to explore more functional materials and deeper Earth's interior.Pressure generated by normal tungsten carbide(WC)anvils in a commercial way is mostly limited to 25 GPa in LVPs due to the limitation of their hardness and design of cell assemblies.We adopt three newly developed WC anvils for ultrahigh pressure generation in a Walker-type LVP with a maximum press load of 1000 ton.The hardest ZK01F WC anvils exhibit the highest efficiency of pressure generation than ZK10F and ZK20F WC anvils,which is related to their performances of plastic deformations.Pressure up to 35 GPa at room temperature is achieved at a relatively low press load of 4.5 MN by adopting the hardest ZK01F WC anvils with three tapering surfaces in conjunction with an optimized cell assembly,while pressure above 35 GPa at 1700 K is achieved at a higher press load of 7.5 MN.Temperature above 2000 K can be generated by our cell assemblies at pressure below 30 GPa.We adopt such high-pressure and high-temperature techniques to fabricate several high-quality and well-sintered polycrystalline minerals for practical use.The present development of high-pressure techniques expands the pressure and temperature ranges in Walker-type LVPs and has wide applications in physics,materials,chemistry,and Earth science.展开更多
文摘The high-pressure diagram of V–N compounds is enriched by proposed seven new stable high-pressure phases.The P-1-VN_4with the armchair N-rich structure may be quenched to ambient conditions.The formed N–N covalent bond plays an important role for the structural stability of N-chain.The charge transfer results in a V–N ionic bond interaction,which further improves the stability of N-chain structure.The P-1-VN_4,P4mnc-VN_8,and Immm-VN_(10)with the outstanding detonation properties have potential application in explosive field.
基金Supported by the National Natural Science Foundation of China(Grant Nos.51320105007,11634004 and 41902034)the Fundamental Research Funds for the Central Universities of China(Grant No.45119031C037)the Program for Changjiang Scholars and Innovative Research Team in University(Grant No.IRT1132).
文摘Pressure generation to a higher pressure range in a large-volume press(LVP)denotes our ability to explore more functional materials and deeper Earth's interior.Pressure generated by normal tungsten carbide(WC)anvils in a commercial way is mostly limited to 25 GPa in LVPs due to the limitation of their hardness and design of cell assemblies.We adopt three newly developed WC anvils for ultrahigh pressure generation in a Walker-type LVP with a maximum press load of 1000 ton.The hardest ZK01F WC anvils exhibit the highest efficiency of pressure generation than ZK10F and ZK20F WC anvils,which is related to their performances of plastic deformations.Pressure up to 35 GPa at room temperature is achieved at a relatively low press load of 4.5 MN by adopting the hardest ZK01F WC anvils with three tapering surfaces in conjunction with an optimized cell assembly,while pressure above 35 GPa at 1700 K is achieved at a higher press load of 7.5 MN.Temperature above 2000 K can be generated by our cell assemblies at pressure below 30 GPa.We adopt such high-pressure and high-temperature techniques to fabricate several high-quality and well-sintered polycrystalline minerals for practical use.The present development of high-pressure techniques expands the pressure and temperature ranges in Walker-type LVPs and has wide applications in physics,materials,chemistry,and Earth science.
