The structural and electronic properties of bulk and (001) plane of TiC were investigated by the first-principles total-energy pseudopotential method based on density functional theory.The calculated bulk properties i...The structural and electronic properties of bulk and (001) plane of TiC were investigated by the first-principles total-energy pseudopotential method based on density functional theory.The calculated bulk properties indicate that bonding nature in TiC is a combination of ionicity,covalency and metallicity,in which the Ti-C covalent bonding is the predominate one.The calculated results of structural relaxation and surface energy for TiC(001) slab indicate that slab with 7 layers shows bulk-like characteristic interiors,and the changes of slab occur on the outmost three layers,which shows that the relaxation only influences the top three layers.Meanwhile,the strong Ti-C covalent bonding can be found in the distribution of charge density on the (110) and (001) planes.Ti-C covalent bonding is enhanced by the charge depletion and accumulation in the vacuum and the interlayer region between top two atomic layers.展开更多
基于检测物与电极之间直接相互作用的第3代生物传感器是当前研究的热点.文中采用SCC-DFTB与DFT结合的方法,对ZnO量子点与尿酸分子的界面特性进行了理论研究,结果显示ZnO量子点上的锌原子与尿酸分子中的氧原子之间有较强的相互作用,最优...基于检测物与电极之间直接相互作用的第3代生物传感器是当前研究的热点.文中采用SCC-DFTB与DFT结合的方法,对ZnO量子点与尿酸分子的界面特性进行了理论研究,结果显示ZnO量子点上的锌原子与尿酸分子中的氧原子之间有较强的相互作用,最优化结构的结合能达到了1.59 e V;通过Bader电荷分析,发现ZnO量子点与尿酸分子界面间的转移电荷量为0.344 e.基于理论计算结果,文中以能量捕获或电信号为切入点,对使用ZnO量子点直接检测尿酸分子的传感器进行了初步探讨.展开更多
基金Project(200802015) supported by Post-doctoral Foundation of Shandong Province,ChinaProject(50625101) supported by the National Natural Science Foundation for Distinguished Young Scholars of China
文摘The structural and electronic properties of bulk and (001) plane of TiC were investigated by the first-principles total-energy pseudopotential method based on density functional theory.The calculated bulk properties indicate that bonding nature in TiC is a combination of ionicity,covalency and metallicity,in which the Ti-C covalent bonding is the predominate one.The calculated results of structural relaxation and surface energy for TiC(001) slab indicate that slab with 7 layers shows bulk-like characteristic interiors,and the changes of slab occur on the outmost three layers,which shows that the relaxation only influences the top three layers.Meanwhile,the strong Ti-C covalent bonding can be found in the distribution of charge density on the (110) and (001) planes.Ti-C covalent bonding is enhanced by the charge depletion and accumulation in the vacuum and the interlayer region between top two atomic layers.
文摘基于检测物与电极之间直接相互作用的第3代生物传感器是当前研究的热点.文中采用SCC-DFTB与DFT结合的方法,对ZnO量子点与尿酸分子的界面特性进行了理论研究,结果显示ZnO量子点上的锌原子与尿酸分子中的氧原子之间有较强的相互作用,最优化结构的结合能达到了1.59 e V;通过Bader电荷分析,发现ZnO量子点与尿酸分子界面间的转移电荷量为0.344 e.基于理论计算结果,文中以能量捕获或电信号为切入点,对使用ZnO量子点直接检测尿酸分子的传感器进行了初步探讨.