By using scanning tunneling microscope/microscopy(STM/STS), we reveal the detailed electronic structures around the sharp edges and strained terraces of lateral monolayer-bilayer Pd_(2)Se_(3) heterostructures. We find...By using scanning tunneling microscope/microscopy(STM/STS), we reveal the detailed electronic structures around the sharp edges and strained terraces of lateral monolayer-bilayer Pd_(2)Se_(3) heterostructures. We find that the edges of such heterostructures are well-defined zigzag type. Band bending and alignment are observed across the zigzag edge, forming a monolayer-bilayer heterojunction. In addition, an n-type band bending is induced by strain on a confined bilayer Pd_(2)Se_(3) terrace. These results provide effective toolsets to tune the band structures in Pd_(2)Se_(3)-based heterostructures and devices.展开更多
Two-dimensional(2D)materials received large amount of studies because of the enormous potential in basic science and industrial applications.Monolayer Pd2Se3 is a fascinating 2D material that was predicted to possess ...Two-dimensional(2D)materials received large amount of studies because of the enormous potential in basic science and industrial applications.Monolayer Pd2Se3 is a fascinating 2D material that was predicted to possess excellent thermoelectric,electronic,transport,and optical properties.However,the fabrication of large-scale and high-quality monolayer Pd2Se3 is still challenging.Here,we report the synthesis of large-scale and high-quality monolayer Pd2Se3 on graphene-SiC(0001)by a two-step epitaxial growth.The atomic structure of Pd2Se3 was investigated by scanning tunneling microscope(STM)and confirmed by non-contact atomic force microscope(nc-AFM).Two subgroups of Se atoms have been identified by nc-AFM image in agreement with the theoretically predicted atomic structure.Scanning tunneling spectroscopy(STS)reveals a bandgap of 1.2 eV,suggesting that monolayer Pd2Se3 can be a candidate for photoelectronic applications.The atomic structure and defect levels of a single Se vacancy were also investigated.The spatial distribution of STS near the Se vacancy reveals a highly anisotropic electronic behavior.The two-step epitaxial synthesis and characterization of Pd2Se3 provide a promising platform for future investigations and applications.展开更多
Majorana zero modes(MZMs) are Majorana-fermion-like quasiparticles existing in crystals or hybrid platforms with topologically non-trivial electronic structures. They obey non-Abelian braiding statistics and are consi...Majorana zero modes(MZMs) are Majorana-fermion-like quasiparticles existing in crystals or hybrid platforms with topologically non-trivial electronic structures. They obey non-Abelian braiding statistics and are considered promising to realize topological quantum computing. Discovery of MZM in the vortices of the iron-based superconductors(IBSs)has recently fueled the Majorana research in a way which not only removes the material barrier requiring construction of complicated hybrid artificial structures, but also enables observation of pure MZMs under higher temperatures. So far,MZMs have been observed in iron-based superconductors including FeTe_(0.55)Se_(0.45),(Li_(0.84)Fe_(0.16))OHFe Se, Ca KFe_(4)As_(4),and Li Fe As. In this topical review, we present an overview of the recent STM studies on the MZMs in IBSs. We start with the observation of MZMs in the vortices in FeTe_(0.55)Se_(0.45)and discuss the pros and cons of FeTe_(0.55)Se_(0.45) compared with other platforms. We then review the following up discovery of MZMs in vortices of Ca KFe_(4)As_(4), impurity-assisted vortices of Li Fe As, and quantum anomalous vortices in FeTe_(0.55)Se_(0.45), illustrating the pathway of the developments of MZM research in IBSs. Finally, we give perspective on future experimental works in this field.展开更多
基金Project supported by the National Key Research and Development Project of China(Grant Nos.2016YFA0202300,2018YFA0305800,and 2019YFA0308500)the National Natural Science Foundation of China(Grant Nos.61888102 and 52022105)+1 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(Grant Nos.XDB30000000 and XDB28000000)the University of Chinese Academy of Sciences。
文摘By using scanning tunneling microscope/microscopy(STM/STS), we reveal the detailed electronic structures around the sharp edges and strained terraces of lateral monolayer-bilayer Pd_(2)Se_(3) heterostructures. We find that the edges of such heterostructures are well-defined zigzag type. Band bending and alignment are observed across the zigzag edge, forming a monolayer-bilayer heterojunction. In addition, an n-type band bending is induced by strain on a confined bilayer Pd_(2)Se_(3) terrace. These results provide effective toolsets to tune the band structures in Pd_(2)Se_(3)-based heterostructures and devices.
基金Project supported by the National Key Research and Development Program of China(Grant Nos.2016YFA0202300,2018YFA0305800,and 2019YFA0308500)the National Natural Science Foundation of China(Grant Nos.51922011,51872284,and 61888102)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDB30000000 and XDB28000000)the Science Fund from University of the Chinese Academy of Sciences.
文摘Two-dimensional(2D)materials received large amount of studies because of the enormous potential in basic science and industrial applications.Monolayer Pd2Se3 is a fascinating 2D material that was predicted to possess excellent thermoelectric,electronic,transport,and optical properties.However,the fabrication of large-scale and high-quality monolayer Pd2Se3 is still challenging.Here,we report the synthesis of large-scale and high-quality monolayer Pd2Se3 on graphene-SiC(0001)by a two-step epitaxial growth.The atomic structure of Pd2Se3 was investigated by scanning tunneling microscope(STM)and confirmed by non-contact atomic force microscope(nc-AFM).Two subgroups of Se atoms have been identified by nc-AFM image in agreement with the theoretically predicted atomic structure.Scanning tunneling spectroscopy(STS)reveals a bandgap of 1.2 eV,suggesting that monolayer Pd2Se3 can be a candidate for photoelectronic applications.The atomic structure and defect levels of a single Se vacancy were also investigated.The spatial distribution of STS near the Se vacancy reveals a highly anisotropic electronic behavior.The two-step epitaxial synthesis and characterization of Pd2Se3 provide a promising platform for future investigations and applications.
基金supported by the Ministry of Science and Technology of China (Grant No. 2019YFA0308500)the Chinese Academy of Sciences (Grant Nos. XDB28000000 and YSBR-003)。
文摘Majorana zero modes(MZMs) are Majorana-fermion-like quasiparticles existing in crystals or hybrid platforms with topologically non-trivial electronic structures. They obey non-Abelian braiding statistics and are considered promising to realize topological quantum computing. Discovery of MZM in the vortices of the iron-based superconductors(IBSs)has recently fueled the Majorana research in a way which not only removes the material barrier requiring construction of complicated hybrid artificial structures, but also enables observation of pure MZMs under higher temperatures. So far,MZMs have been observed in iron-based superconductors including FeTe_(0.55)Se_(0.45),(Li_(0.84)Fe_(0.16))OHFe Se, Ca KFe_(4)As_(4),and Li Fe As. In this topical review, we present an overview of the recent STM studies on the MZMs in IBSs. We start with the observation of MZMs in the vortices in FeTe_(0.55)Se_(0.45)and discuss the pros and cons of FeTe_(0.55)Se_(0.45) compared with other platforms. We then review the following up discovery of MZMs in vortices of Ca KFe_(4)As_(4), impurity-assisted vortices of Li Fe As, and quantum anomalous vortices in FeTe_(0.55)Se_(0.45), illustrating the pathway of the developments of MZM research in IBSs. Finally, we give perspective on future experimental works in this field.
