A new cyano-bridged GadoliniumⅢ-IronⅢ complex {[Gd(DMF)3(DMSO)(H2O)3](250 78(3) nm, c=1.413 03(1) nm, 穋m-3, Z=2, Mr=756.72, F(000)=760, Ⅲ) and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ) ar...A new cyano-bridged GadoliniumⅢ-IronⅢ complex {[Gd(DMF)3(DMSO)(H2O)3](250 78(3) nm, c=1.413 03(1) nm, 穋m-3, Z=2, Mr=756.72, F(000)=760, Ⅲ) and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ) are linked by a cyano-bridge group to construct a dinuclear compound. The {[Gd(DMF)3(DMSO)(H2O)3](Ⅲ)-Fe(Ⅲ) interaction is antiferromagnetic. CCDC: 223430.展开更多
基金This work was supported by the National Key R&D Program of China(No.2016YFA0200601)the National Natural Science Foundation of China(No.21790352)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB36000000)the Anhui Initiative in Quantum Information Technologies(No.AHY090100).
基金Author to whom correspondence should be addressed. E-mail: zcdong@ustc.edu.cn, FAX: +86-551-3600103 This work was supported by the National Basic Research Program of China (No.2006CB922003 and No.2011CB921402), the Chinese Academy of Sciences (No.KJCX2.YW.H06), and the National Natural Science Foundation of China (No.91021004, No.10574117, and No.10974186).
基金This work was supported by the National Key R&D Program of China(No.2016YFA0200600)the National Natural Science Foundation of China,the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB36000000)the Anhui Initiative in Quantum Information Technologies.
文摘A new cyano-bridged GadoliniumⅢ-IronⅢ complex {[Gd(DMF)3(DMSO)(H2O)3](250 78(3) nm, c=1.413 03(1) nm, 穋m-3, Z=2, Mr=756.72, F(000)=760, Ⅲ) and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ) are linked by a cyano-bridge group to construct a dinuclear compound. The {[Gd(DMF)3(DMSO)(H2O)3](Ⅲ)-Fe(Ⅲ) interaction is antiferromagnetic. CCDC: 223430.