The relationship between U-Ti formation heats and mole fraction of Ti was obtained by Miedema’s model.△mixSE,△mixGE and activity coefficient of the system were calculated based on the free volume theory considering...The relationship between U-Ti formation heats and mole fraction of Ti was obtained by Miedema’s model.△mixSE,△mixGE and activity coefficient of the system were calculated based on the free volume theory considering excess entropy and some basic relationships of thermodynamics.The results indicate that U-Ti solution has negative deviation to ideal solution,and the deviation should increase with the decrease of temperature.展开更多
文摘The relationship between U-Ti formation heats and mole fraction of Ti was obtained by Miedema’s model.△mixSE,△mixGE and activity coefficient of the system were calculated based on the free volume theory considering excess entropy and some basic relationships of thermodynamics.The results indicate that U-Ti solution has negative deviation to ideal solution,and the deviation should increase with the decrease of temperature.