Acetic acid was selected as the model compound representing the carboxylic acids present in bio-oil.This work focuses the co-cracking of acetic acid with ethanol for bio-gasoline production.The influences of reaction ...Acetic acid was selected as the model compound representing the carboxylic acids present in bio-oil.This work focuses the co-cracking of acetic acid with ethanol for bio-gasoline production.The influences of reaction temperature and pressure on the conversion of reactants as well as the selectivity and composition of the crude gasoline phase were investigated.It was found that increasing reaction temperature benefited the conversion of reactants and pressurized cracking produced a higher crude gasoline yield.At 400°C and 1 MPa,the conversion of the reactants reached over 99%and the selectivity of the gasoline phase reached 42.79%(by mass).The gasoline phase shows outstanding quality,with a hydrocarbon content of 100%.展开更多
基金Supported by the National Natural Science Foundation of China(51276166)the National Science Technology Supporting Plan Through Contract(2011BAD22B06)+1 种基金the Zhejiang Provincial Natural Science Foundation(R1110089)the Program for New Century Excellent Talents in University(NCET-10-0741)
文摘Acetic acid was selected as the model compound representing the carboxylic acids present in bio-oil.This work focuses the co-cracking of acetic acid with ethanol for bio-gasoline production.The influences of reaction temperature and pressure on the conversion of reactants as well as the selectivity and composition of the crude gasoline phase were investigated.It was found that increasing reaction temperature benefited the conversion of reactants and pressurized cracking produced a higher crude gasoline yield.At 400°C and 1 MPa,the conversion of the reactants reached over 99%and the selectivity of the gasoline phase reached 42.79%(by mass).The gasoline phase shows outstanding quality,with a hydrocarbon content of 100%.