It would play an important role in understanding molecular active functions to studybimolecular intermotion.<sup>13</sup>C longitudinal relaxation which could reflect information of mo-lecular or intermole...It would play an important role in understanding molecular active functions to studybimolecular intermotion.<sup>13</sup>C longitudinal relaxation which could reflect information of mo-lecular or intermolecular motion provides a very powerful technique for the study of molecu-lar motion. In this note, the <sup>13</sup>C longitudinal relaxation time （T<sub>1</sub>） and NOE values of oxi-dized and reduced glutathione （GSSG and GSH） have been measured under the conditionsof different temperatures and magnetic fields. The various relaxation mechanisms wereseparated. and rotational active energies of carbons were calculated. It is studied for展开更多
基金Project supported by the National Natural Science Foundation of China and State Key Laboratory of Physical Organic Chemist,Lanzhou University.
文摘It would play an important role in understanding molecular active functions to studybimolecular intermotion.<sup>13</sup>C longitudinal relaxation which could reflect information of mo-lecular or intermolecular motion provides a very powerful technique for the study of molecu-lar motion. In this note, the <sup>13</sup>C longitudinal relaxation time （T<sub>1</sub>） and NOE values of oxi-dized and reduced glutathione （GSSG and GSH） have been measured under the conditionsof different temperatures and magnetic fields. The various relaxation mechanisms wereseparated. and rotational active energies of carbons were calculated. It is studied for
