C MAS NMR has been performed in situ to investigate the activation of 13C labeled propane under a mild condition over Ga-modified H-ZSM-5 catalysts prepared via different methods. The results indicate that the ion-exc...C MAS NMR has been performed in situ to investigate the activation of 13C labeled propane under a mild condition over Ga-modified H-ZSM-5 catalysts prepared via different methods. The results indicate that the ion-exchanged and/or its related Ga species are the highly active catalytic components, while impregnated Ga species is not the active species for propane activation at 573 K.展开更多
文摘C MAS NMR has been performed in situ to investigate the activation of 13C labeled propane under a mild condition over Ga-modified H-ZSM-5 catalysts prepared via different methods. The results indicate that the ion-exchanged and/or its related Ga species are the highly active catalytic components, while impregnated Ga species is not the active species for propane activation at 573 K.
基金supported by the National Key Basic Research Program of China(973)(2009CB623506)National High Technology Research andDevelopment Program of China(863)(2009AA033701)+1 种基金Program of Shanghai Subject Chief Scientist,China(10XD1400300)ShanghaiLeading Academic Discipline Project,China(B108)~~
基金Supported by the National Natural Science Foundation of China(G20503005,20473021,20421303),the National Basic Research Programof China(2003CB615807)and the Research Fund for the Doctoral Programof Higher Education(20050246071).
