微波活化对Ca(OH)_2孔隙结构及脱氯性能的影响

采用微波炉对一定质量的氧氧化钙样品进行活化，利用压汞仪考察了不同微波活化时川及脱氯反应前后的Ca（OH）2总比孔表而积、分段比表面积和孔径分布的变化，并在脱氯实验台上对脱氯效率进行实际测试。结果表明，微波活化存在一个最佳时间，在此时间内样品比孔表面积增大50％左右，而超过这一时间样品比表面积回复性减小；微波活化主要通过增加3～20nm孔径段的微孔为样品提供更大比表面积；这些新增加的微孔在脱氯反应过程中被完全利用或消耗；最佳活化时间下的微波活化使Ca（OH）2住较低Ca／Cl摩尔比下获得更大脱氯效率，Ca／Cl摩尔比=4．1时，脱氯效率增加了20％。

面向应急保障的5G网联无人机关键技术

针对现有的应急保障通信系统在自然灾害发生时,存在覆盖范围小、因道路受阻无法到达灾区、供电时间短等问题。提出了5G+空天地一体化应急保障体系,采用5G网联无人机(unmanned aerial vehicle, UAV)覆盖优化技术,可以有效提高连续覆盖性、增强移动性、减少时延;并在此体系框架内设计了一种网联无人机应急通信方案,利用大型固定翼无人机搭载无线通讯基站,采用卫星传输,构建了应急空天基站,实现任何时间、地点,全天候提供大面积覆盖的应急通信保障,具有更高效率、更长续航、更广覆盖、更大载荷等优势。从理论上分析了此方案中关键覆盖技术的有效覆盖半径和飞行速度,并通过飞行测试验证其有效性。测试结果表明该方案可以满足用户的通话、视频业务需求,为无人机在应急保障领域的应用实践提供参考。

垃圾水分对垃圾焚烧过程重金属迁移转化影响的实验研究(英文)

The effect of moisture in municipal solid waste (MSW) on partitioning of lead (Pb), zinc (Zn), copper (Cu) and cadmium (Cd) was studied in a laboratory tubular furnace by using simulated MSW. The moisture in MSW influences heavy metals in following ways, to increase the moisture in flue gas and decrease the combustion temperature, to prolong the combustion time, and to prolong the releasing time of volatiles with the furnace temperature decreased by increasing the moisture. The volatilization of Pb, Zn and Cd was enhanced by increasing the moisture in MSW because of the prolonged combustion time. For Pb and Zn, the combustion time was important at higher temperature, while for Cd, it was important at low temperature. The moisture content showed slight effect on Cu partitioning. When extra chlorine was added to MSW, such as 1%PVC + 0.5%NaCl, the volatilization of Pb, Zn and Cu was enhanced by increasing the moisture because water evaporation reduced the temperature and increased devolatilization time. At higher temperature, NaCl tends to decompose and generates more free chlorine, producing more metal chlorides. Since Cd is a strong volatile heavy metal in MSW, the effect of moisture content on its volatilization is less than that of Pb, Zn or Cu during the MSW incineration.