By utlixing the magnetic interactions possessing C3v Symmetry,the author deduced the general expressions for the g-factors,Zero-field splitting and effective magnetic moment of the ground subgket irbutak state ub d^3-...By utlixing the magnetic interactions possessing C3v Symmetry,the author deduced the general expressions for the g-factors,Zero-field splitting and effective magnetic moment of the ground subgket irbutak state ub d^3-complex.For ruby(Al2O3:Cr^3+)the results are in good agreement with experiments;theoretical values:g∥=1.9835,g┴=1.9876;2D=-0.373cm^-1,μ∥=3.857β,μ┴=3.861β;Expcrimental values:g∥=1.9840±0.0006,g┴=1.9867+0.0006;2D=-0.3831±0.0002cm^-1;β=3.8-3.9β.展开更多
文摘By utlixing the magnetic interactions possessing C3v Symmetry,the author deduced the general expressions for the g-factors,Zero-field splitting and effective magnetic moment of the ground subgket irbutak state ub d^3-complex.For ruby(Al2O3:Cr^3+)the results are in good agreement with experiments;theoretical values:g∥=1.9835,g┴=1.9876;2D=-0.373cm^-1,μ∥=3.857β,μ┴=3.861β;Expcrimental values:g∥=1.9840±0.0006,g┴=1.9867+0.0006;2D=-0.3831±0.0002cm^-1;β=3.8-3.9β.
