Monodisperse sodium yttrium fluoride com sticks with hexagonal nanostructure were successfully prepared by a facile and repeatable precipitation transformation method. The phase and morphology of the products were cha...Monodisperse sodium yttrium fluoride com sticks with hexagonal nanostructure were successfully prepared by a facile and repeatable precipitation transformation method. The phase and morphology of the products were characterized with X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The growth mechanism was studied, indicating that the initial generated Y（OH）3 gradually translated into YF3 and then transformed into com stick-like H-NaYF4 nanoparticles owing to the crucial role of fluorine ions in the solution. The up-conversion （UC） luminescence properties of H-NaYF4：20%Yb3＋,2%Er3＋ nanocrystals were discussed. The intensive green emission in the range of 510-570 nm was attributed to the （2Hll/2, 4S3/2）----4It5/2 transition and the weaker red emission between 640 and 680 nm was originating from the 4F9/2----4115/2 transition.展开更多
基金Project(51202066)supported by the National Natural Science Foundation of ChinaProject(NCET-13-0784)supported by the Program for New Century Excellent Talents of the Education Ministry,China。
基金supported by the National Natural Science Foundation(NSF)of China(51202066)Program for New Century Excellent Talents supported by the China Education Ministry(NCET-13-0784)+5 种基金Study Abroad Program sponsored by China Scholarship Council(201308430385)Scientific Research Fund of Hunan Provincial Education Department(12A047)Research of Science and Technology Department of Hunan Province(2013SK3162)State Key Laboratory Program of Rare Earth Resource Utilization of China(RERU2013019)State Key Laboratory Programs of Inorganic Synthesis and Preparative Chemistry of China(2013-26)Key Laboratory Program of Ecological Impacts of Hydraulic-projects and Restoration of Aquatic Ecosystem in Ministry of Water Resources of China(2013001)
文摘Monodisperse sodium yttrium fluoride com sticks with hexagonal nanostructure were successfully prepared by a facile and repeatable precipitation transformation method. The phase and morphology of the products were characterized with X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The growth mechanism was studied, indicating that the initial generated Y（OH）3 gradually translated into YF3 and then transformed into com stick-like H-NaYF4 nanoparticles owing to the crucial role of fluorine ions in the solution. The up-conversion （UC） luminescence properties of H-NaYF4：20%Yb3＋,2%Er3＋ nanocrystals were discussed. The intensive green emission in the range of 510-570 nm was attributed to the （2Hll/2, 4S3/2）----4It5/2 transition and the weaker red emission between 640 and 680 nm was originating from the 4F9/2----4115/2 transition.
