Surface tension of molten Ni-(Cr,Co,W) alloys was measured at the temperature of 1 773-1 873 K in an Ar+3%H2 atmosphere using an improved sessile drop method.The segregation of Cr,Co and W in alloy was calculated and ...Surface tension of molten Ni-(Cr,Co,W) alloys was measured at the temperature of 1 773-1 873 K in an Ar+3%H2 atmosphere using an improved sessile drop method.The segregation of Cr,Co and W in alloy was calculated and analyzed using Butler's equation.The results show a good agreement between measured and calculated data.The surface tension of molten Ni-(Cr,Co,W) alloys decreases with increasing temperature.In Ni-(Cr,Co,W) alloys,the element with lower surface tension tends to segregate on the surface of molten alloy while that with higher surface tension tends to segregate inside of the molten alloy.The larger the differences in surface tension,atom radius and electron configuration between solvent and solute are,the more significant the segregation is.As a result,Ni segregates onto the surface and Co and W segregate inside the alloys.展开更多
基金Supported by Scientific Research Foundation for the Returned Overseas Chinese Scholars(2004527)the Chongqing Bureau of Personal(200594)+1 种基金the Natural Science Foundation of Chongqing Municipality(CSTC2005BA4016-1)the Chongqing Institute of Technology(2003ZD31)
基金Project(2004527) supported by Scientific Research Foundation for the Returned Overseas Chinese ScholarsProject(200594) supported by the Chongqing Bureau of Personal, China+2 种基金Project(KJ070603) supported by the Municipal Education Commission of Chongqing, ChinaProject(2003ZD31) supported by Chongqing Institute of Technology, ChinaProject(CSTC2005BA4016-1) supported by Chongqing Science and Technology Commission,China
文摘Surface tension of molten Ni-(Cr,Co,W) alloys was measured at the temperature of 1 773-1 873 K in an Ar+3%H2 atmosphere using an improved sessile drop method.The segregation of Cr,Co and W in alloy was calculated and analyzed using Butler's equation.The results show a good agreement between measured and calculated data.The surface tension of molten Ni-(Cr,Co,W) alloys decreases with increasing temperature.In Ni-(Cr,Co,W) alloys,the element with lower surface tension tends to segregate on the surface of molten alloy while that with higher surface tension tends to segregate inside of the molten alloy.The larger the differences in surface tension,atom radius and electron configuration between solvent and solute are,the more significant the segregation is.As a result,Ni segregates onto the surface and Co and W segregate inside the alloys.