Synthesis gas(syngas),a fundamental feedstock in chemical industry,is a mixture of hydrogen(H2)and carbon monoxide(CO).Transition metal-catalyzed hydroformylation of alkenes with syngas has been an important industria...Synthesis gas(syngas),a fundamental feedstock in chemical industry,is a mixture of hydrogen(H2)and carbon monoxide(CO).Transition metal-catalyzed hydroformylation of alkenes with syngas has been an important industrial process in the production of aldehydes and their derivatives,such as carboxylic acids,alcohols and amines(Fig.1 a)[1].Large-scale consumption of syngas in industrial hydroformylations contributes to approximately 12 million tons of oxo products annually[2].展开更多
基金supported by the National Natural Science Foundation of China(22061029,22062015,and 21975135)Young Scientist Fund of Natural Science Foundation of Jiangsu Province(BK20180248)Ph.D.Start-up Fund of Natural Science Foundation of Guangdong Province(2018A03031061)。
文摘Synthesis gas(syngas),a fundamental feedstock in chemical industry,is a mixture of hydrogen(H2)and carbon monoxide(CO).Transition metal-catalyzed hydroformylation of alkenes with syngas has been an important industrial process in the production of aldehydes and their derivatives,such as carboxylic acids,alcohols and amines(Fig.1 a)[1].Large-scale consumption of syngas in industrial hydroformylations contributes to approximately 12 million tons of oxo products annually[2].
