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固态薄膜电解质LiSiPON和其性能研究 被引量:2
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作者 申万 杨志民 +2 位作者 邢光健 毛昌辉 杜军 《电源技术》 CAS CSCD 北大核心 2006年第3期179-182,共4页
用0.5Li3PO4-0.5Li2SiO3为靶材,用射频磁控溅射的方法在N2气氛中制备了非晶结构的固态电解质LiSiPON薄膜。N和Si的引入提高了Li2O-P2O5体系的离子电导率,在室温时电解质薄膜的离子电导率为4.83×10-6S/cm。LiSiPON电解质薄膜与Pt的... 用0.5Li3PO4-0.5Li2SiO3为靶材,用射频磁控溅射的方法在N2气氛中制备了非晶结构的固态电解质LiSiPON薄膜。N和Si的引入提高了Li2O-P2O5体系的离子电导率,在室温时电解质薄膜的离子电导率为4.83×10-6S/cm。LiSiPON电解质薄膜与Pt的分解压为5.7V左右,是一种很有潜力的应用于全固态薄膜锂离子蓄电池的电解质材料。 展开更多
关键词 LiSiPON 固态电解质 薄膜 射频磁控溅射 锂离子蓄电池
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Influence of deposition temperature on ionic conductivity of perovskite (Li_(0.5)La_(0.5))TiO_3 solid state electrolyte thin film
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作者 申万 杨志民 +2 位作者 邢光健 毛昌辉 杜军 《广东有色金属学报》 2005年第2期439-443,共5页
Thin film microbattery is a promising micropower source for its high energy density and good cell performances, and the application of fast lithium ion conducting solids as electrolytes is thus very important. (Li 0.... Thin film microbattery is a promising micropower source for its high energy density and good cell performances, and the application of fast lithium ion conducting solids as electrolytes is thus very important. (Li 0.5 La 0.5 )TiO3 (LLTO) thin film electrolytes for thin film microbattery were prepared onto Pt/Si substrates using magnetron sputtering. As-deposited LLTO thin films showed amorphous-like phases and when deposition temperature increases the ionic conductivity raises accordingly. The ionic conductivity of LLTO thin film reaches 8.7×10 -6 S/cm when the deposition temperature is 400℃, which shows that the LLTO thin films deposited by magnetron sputtering are suitable for application as an electrolyte for thin film microbattery. 展开更多
关键词 薄膜 电极 固相 电池 离子传导性
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