With the pretreatment of pyrolysis, the uniform, smooth, dense and crack free Gd2O3∶Eu3+ films were obtained by sol-gel process without shielding atmosphere. Atomic force microscopy （AFM）, X-ray diffraction （XRD）...With the pretreatment of pyrolysis, the uniform, smooth, dense and crack free Gd2O3∶Eu3+ films were obtained by sol-gel process without shielding atmosphere. Atomic force microscopy （AFM）, X-ray diffraction （XRD）, Ellipsometry, transmission, photoluminescence and X-ray excited emission were applied to study to the surface morphology, structure, thickness and optical properties of the films. The results show that the films are made up of grains with cubic structure in average size about 22 nm. With 21 times reproducible spin coating and pyrolysis treatment, the thickness of the film could reach to 792 nm and the transmittance of the film in visible region is above 90%. Two peaks at 223 and 250 nm are found in excitation spectra, which correspond to host lattice （HL） excitation and charge transfer （CT） excitation, respectively. Meanwhile, the main peak relates to HL excitation which is contrary to that of Gd2O3∶Eu3+ powder. This phenomenon will be beneficial to radioluminescence. The emission spectra show that the main peak located at 611 nm could be excited either by UV or X-ray, which correspond to （（）7F2→（）5D0） transition in Eu3+ ions. The luminescence intensity at 10 ms is only 10-4 time of that at 10 μs, which means that the afterglow in Gd2O3∶Eu3+ films is insignificant for X-ray imaging.展开更多
针对地球物理勘探中高精度磁场测量以及远距离数据同步的需求,本文基于低温超导量子干涉仪和图形化系统开发平台构建了一种可通过GPS同步的新型磁力仪,并可采用简便的直读方式进行磁场测量。首先介绍了新型低温超导磁力仪的工作原理,并...针对地球物理勘探中高精度磁场测量以及远距离数据同步的需求,本文基于低温超导量子干涉仪和图形化系统开发平台构建了一种可通过GPS同步的新型磁力仪,并可采用简便的直读方式进行磁场测量。首先介绍了新型低温超导磁力仪的工作原理,并重点阐述了由其程控直读电路以及软硬件设计方案;然后在分析影响超导磁力仪数据同步因素的基础上,给出了GPS同步实现及其同步精度标定的方法;最后在良好的磁屏蔽环境中对超导磁力仪的性能以及电磁兼容进行了评估,并对影响其同步的相关因素进行了测试和标定,试验表明传感器的本底噪声约为6 f T/Hz@1 kHz,数据同步精度可达1 ms,满足实用要求。展开更多
Using a second-order helium-cooled superconducting quantum interference device gradiometer as the detector,ultra-low-field nuclear magnetic resonance(ULF-NMR)signals of protons are recorded in an urban environment wit...Using a second-order helium-cooled superconducting quantum interference device gradiometer as the detector,ultra-low-field nuclear magnetic resonance(ULF-NMR)signals of protons are recorded in an urban environment without magnetic shielding.The homogeneity and stability of the measurement field are investigated.NMR signals of protons are studied at night and during working hours.The Larmor frequency variation caused by the fluctuation of the external magnetic field during daytime reaches around 5 Hz when performing multiple measurements for about 10 min,which seriously affects the results of averaging.In order to improve the performance of the averaged data,we suggest the use of a data processor,i.e.the so-called time-domain frequency correction(TFC).For a 50-times averaged signal spectrum,the signal-to-noise ratio is enhanced from 30 to 120 when applying TFC while preserving the NMR spectrum linewidth.The TFC is also applied successfully to the measurement data of the hetero-nuclear J-coupling in 2,2,2-trifluoroethanol.展开更多
文摘With the pretreatment of pyrolysis, the uniform, smooth, dense and crack free Gd2O3∶Eu3+ films were obtained by sol-gel process without shielding atmosphere. Atomic force microscopy （AFM）, X-ray diffraction （XRD）, Ellipsometry, transmission, photoluminescence and X-ray excited emission were applied to study to the surface morphology, structure, thickness and optical properties of the films. The results show that the films are made up of grains with cubic structure in average size about 22 nm. With 21 times reproducible spin coating and pyrolysis treatment, the thickness of the film could reach to 792 nm and the transmittance of the film in visible region is above 90%. Two peaks at 223 and 250 nm are found in excitation spectra, which correspond to host lattice （HL） excitation and charge transfer （CT） excitation, respectively. Meanwhile, the main peak relates to HL excitation which is contrary to that of Gd2O3∶Eu3+ powder. This phenomenon will be beneficial to radioluminescence. The emission spectra show that the main peak located at 611 nm could be excited either by UV or X-ray, which correspond to （（）7F2→（）5D0） transition in Eu3+ ions. The luminescence intensity at 10 ms is only 10-4 time of that at 10 μs, which means that the afterglow in Gd2O3∶Eu3+ films is insignificant for X-ray imaging.
文摘针对地球物理勘探中高精度磁场测量以及远距离数据同步的需求,本文基于低温超导量子干涉仪和图形化系统开发平台构建了一种可通过GPS同步的新型磁力仪,并可采用简便的直读方式进行磁场测量。首先介绍了新型低温超导磁力仪的工作原理,并重点阐述了由其程控直读电路以及软硬件设计方案;然后在分析影响超导磁力仪数据同步因素的基础上,给出了GPS同步实现及其同步精度标定的方法;最后在良好的磁屏蔽环境中对超导磁力仪的性能以及电磁兼容进行了评估,并对影响其同步的相关因素进行了测试和标定,试验表明传感器的本底噪声约为6 f T/Hz@1 kHz,数据同步精度可达1 ms,满足实用要求。
基金Supported by the International Cooperation Key Project of Bureau of International Cooperation,CAS,under Grant No GJHZ1104Shanghai Natural Science foundation under Grant No 11ZR1444100.
文摘Using a second-order helium-cooled superconducting quantum interference device gradiometer as the detector,ultra-low-field nuclear magnetic resonance(ULF-NMR)signals of protons are recorded in an urban environment without magnetic shielding.The homogeneity and stability of the measurement field are investigated.NMR signals of protons are studied at night and during working hours.The Larmor frequency variation caused by the fluctuation of the external magnetic field during daytime reaches around 5 Hz when performing multiple measurements for about 10 min,which seriously affects the results of averaging.In order to improve the performance of the averaged data,we suggest the use of a data processor,i.e.the so-called time-domain frequency correction(TFC).For a 50-times averaged signal spectrum,the signal-to-noise ratio is enhanced from 30 to 120 when applying TFC while preserving the NMR spectrum linewidth.The TFC is also applied successfully to the measurement data of the hetero-nuclear J-coupling in 2,2,2-trifluoroethanol.
