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Zn_2SnO_4立方体的水热合成及其荧光性质 被引量:2
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作者 曾毅 邴一飞 +2 位作者 刘畅 郑伟涛 邹广田 《发光学报》 EI CAS CSCD 北大核心 2012年第7期716-719,共4页
利用水合肼作缓释型碱源和络合剂,采用水热法合成了Zn2SnO4立方多面体。XRD物相分析表明,产物为结晶良好的立方反尖晶石结构Zn2SnO4。FESEM和TEM形貌分析表明,该Zn2SnO4微晶为边长100~400 nm左右的立方体,其光致发光光谱是蓝-绿光发射... 利用水合肼作缓释型碱源和络合剂,采用水热法合成了Zn2SnO4立方多面体。XRD物相分析表明,产物为结晶良好的立方反尖晶石结构Zn2SnO4。FESEM和TEM形貌分析表明,该Zn2SnO4微晶为边长100~400 nm左右的立方体,其光致发光光谱是蓝-绿光发射带(中心590 nm处),在400℃空气气氛下退火1 h后,蓝-绿光发射带的强度显著降低。这主要是因为退火处理提高了晶体质量,降低了氧空位浓度,从而降低了可见光发射带的强度。 展开更多
关键词 Zn2SnO4 水热合成 多面体 荧光光谱
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Self-assembly of hierarchical ZnSnO_3-SnO_2 nanoflakes and their gas sensing properties
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作者 曾毅 邴一飞 +2 位作者 刘畅 郑伟涛 邹广田 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第10期2451-2458,共8页
A new type of hierarchical ZnSnO3-SnO2 flower-shaped nanostructure composed of thin nanoflakes as secondary units is successfully prepared through a simple hydrothermal process. The polyhedral ZnSnO3 core acts as a sa... A new type of hierarchical ZnSnO3-SnO2 flower-shaped nanostructure composed of thin nanoflakes as secondary units is successfully prepared through a simple hydrothermal process. The polyhedral ZnSnO3 core acts as a sacrificed template for the growth of hierarchical SnO2 nanoflakes, and the average thickness of SnO2 nanoflakes is around 25 nm. The time-dependent morphology evolution of ZnSnO3-SnO2 samples was investigated, and a possible formation mechanism of these hierarchical structures is discussed. The gas sensor based on these novel ZnSnO3-SnO2 nanostructures exhibits high response and quick response- recovery traits to ethanol (C2H5OH). It is found that ZnSnO3-SnO2 nanoflakes have a response of 27.8 to 50×10-6 C2H5OH at the optimal operating temperature of 270 °C, and the response and recovery time are within 1.0 and 1.8 s, respectively. 展开更多
关键词 complex nanostructure hierarchical structure hydrothermal synthesis gas sensor
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