The influence of Ce addition on the oxidation behavior of 25Cr20Ni alloy at 950 oC under low oxygen partial pressure was inves-tigated. The oxidized samples were characterized by using X-ray diffraction （XRD）, scann...The influence of Ce addition on the oxidation behavior of 25Cr20Ni alloy at 950 oC under low oxygen partial pressure was inves-tigated. The oxidized samples were characterized by using X-ray diffraction （XRD）, scanning electron microscopy （SEM）, energy dispersive X-ray spectroscopy （EDS）, and scratch tester to obtain the oxide phases, morphology, thickness, composition and adhesion property of the oxide scales. The experiment results indicated that a small amount of Ce addition （0.02 wt.% or 0.05 wt.%） promoted oxidation resistance and inhibited the growth of the needlelike oxide. The Ce addition also decreased the formation of MnCr2O4 but promoted the SiO2 formation un-derneath the Cr2O3, which largely contributed to the improvement of oxide scale spallation resistance. For the sample with 0.3 wt.% Ce addi-tion, the oxidation rate significantly increased and the spallation resistance of the oxide scale decreased.展开更多
基金supported by the Basic Research Program of the State Key Laboratory of Heavy Oil Processing (200809),China University of Petroleum, Beijing, China
文摘The influence of Ce addition on the oxidation behavior of 25Cr20Ni alloy at 950 oC under low oxygen partial pressure was inves-tigated. The oxidized samples were characterized by using X-ray diffraction （XRD）, scanning electron microscopy （SEM）, energy dispersive X-ray spectroscopy （EDS）, and scratch tester to obtain the oxide phases, morphology, thickness, composition and adhesion property of the oxide scales. The experiment results indicated that a small amount of Ce addition （0.02 wt.% or 0.05 wt.%） promoted oxidation resistance and inhibited the growth of the needlelike oxide. The Ce addition also decreased the formation of MnCr2O4 but promoted the SiO2 formation un-derneath the Cr2O3, which largely contributed to the improvement of oxide scale spallation resistance. For the sample with 0.3 wt.% Ce addi-tion, the oxidation rate significantly increased and the spallation resistance of the oxide scale decreased.
