Utilizing two polycarboxylic acids as primary ligands and 1,10-phenanthrolion as an auxiliary ligand in the existence of lanthanide nitrates, two lanthanide-based complexes formulated as [Nd4（2,6-pydc OH）6（Phen）4...Utilizing two polycarboxylic acids as primary ligands and 1,10-phenanthrolion as an auxiliary ligand in the existence of lanthanide nitrates, two lanthanide-based complexes formulated as [Nd4（2,6-pydc OH）6（Phen）4（H2O）2]（H2O）2（1） and [Yb2（mBDC）3（Phen）2]n（2）（2,6-H2 pydc OH = 4-hydroxypyridine-2,6-dicarboxylic acid, m-H_2BDC = isophthalic acid, Phen = 1,10-phenanthroline） have been solvothermally synthesized. They have been fully characterized by satisfactory elemental analysis, FT-IR spectra, TGA and single-crystal X-ray diffraction. Single-crystal X-ray diffraction study reveals that 1 has a zero-dimensional structure and 2 exhibits a rare cds topological net structure. Compounds 1 and 2 exhibit strong characteristic emissions of Nd（Ⅲ） and Yb（Ⅲ） ions in the near-infrared（NIR） region.展开更多
基金supported by the National Basic Research Program of China(973 Program,2012CB821702)the National Natural Science Foundation of China(21233009 and 21571175)the State Key Laboratory of Structural Chemistry
文摘Utilizing two polycarboxylic acids as primary ligands and 1,10-phenanthrolion as an auxiliary ligand in the existence of lanthanide nitrates, two lanthanide-based complexes formulated as [Nd4（2,6-pydc OH）6（Phen）4（H2O）2]（H2O）2（1） and [Yb2（mBDC）3（Phen）2]n（2）（2,6-H2 pydc OH = 4-hydroxypyridine-2,6-dicarboxylic acid, m-H_2BDC = isophthalic acid, Phen = 1,10-phenanthroline） have been solvothermally synthesized. They have been fully characterized by satisfactory elemental analysis, FT-IR spectra, TGA and single-crystal X-ray diffraction. Single-crystal X-ray diffraction study reveals that 1 has a zero-dimensional structure and 2 exhibits a rare cds topological net structure. Compounds 1 and 2 exhibit strong characteristic emissions of Nd（Ⅲ） and Yb（Ⅲ） ions in the near-infrared（NIR） region.
