The shape deformation of hydrothermal-grown ZnO nanorods is observed.After annealing at high temperature,hexagonal ZnO nanorods change to become cylinder-like ones.The adjacent nanorods tend to connect to each other t...The shape deformation of hydrothermal-grown ZnO nanorods is observed.After annealing at high temperature,hexagonal ZnO nanorods change to become cylinder-like ones.The adjacent nanorods tend to connect to each other to form one nanostructure.Photoluminescence measurements show that a sample annealed at 600℃has a strong ultraviolet emission with a very weak visible emission,and with increasing annealing temperature the visible emission becomes more intense.It can be concluded from analyses of the morphological changes that the surface reaction between the doped C and ZnO is the main reason for the shape deformation of the ZnO nanorods.展开更多
The influence of voltage on photo-electrochemical etching（PEC） of macroporous silicon arrays（MSA） was researched.According to the theory of the space charge region,I-V scan curves and the reaction mechanism of the...The influence of voltage on photo-electrochemical etching（PEC） of macroporous silicon arrays（MSA） was researched.According to the theory of the space charge region,I-V scan curves and the reaction mechanism of the n-type silicon anodic oxidation in HF solution under different current densities,the pore morphology influenced by the working voltage were studied and analyzed in detail.The results show that increasing the etching voltage will lead to distortion of the pore morphology,decreasing etching voltage will result in an increase in the blind porosity, and the constant etching voltage for a long time will cause gradual bifurcation.Through the optimization of the process parameters,the perfect MSA structure with a pore depth of 317μm,a pore size of 3μm and an aspect ratio of 105 was obtained.展开更多
基金Supported by the National Basic Research Program of China under Grant No 2011CB302004the Innovation Project of the Chinese Academy of Sciences under Grant No KJCX2-YW-W25the National Natural Science Foundation of China under Grant Nos 60506014 and 10974197.
文摘The shape deformation of hydrothermal-grown ZnO nanorods is observed.After annealing at high temperature,hexagonal ZnO nanorods change to become cylinder-like ones.The adjacent nanorods tend to connect to each other to form one nanostructure.Photoluminescence measurements show that a sample annealed at 600℃has a strong ultraviolet emission with a very weak visible emission,and with increasing annealing temperature the visible emission becomes more intense.It can be concluded from analyses of the morphological changes that the surface reaction between the doped C and ZnO is the main reason for the shape deformation of the ZnO nanorods.
基金Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China(No.200801860003)
文摘The influence of voltage on photo-electrochemical etching（PEC） of macroporous silicon arrays（MSA） was researched.According to the theory of the space charge region,I-V scan curves and the reaction mechanism of the n-type silicon anodic oxidation in HF solution under different current densities,the pore morphology influenced by the working voltage were studied and analyzed in detail.The results show that increasing the etching voltage will lead to distortion of the pore morphology,decreasing etching voltage will result in an increase in the blind porosity, and the constant etching voltage for a long time will cause gradual bifurcation.Through the optimization of the process parameters,the perfect MSA structure with a pore depth of 317μm,a pore size of 3μm and an aspect ratio of 105 was obtained.
