An iridium-catalyzed allylic substitution of sodium phenyl selenide with unsymmetrical allyl carbonates was accomplished, which produced the linear allyl phenyl selenides in 38%--74% yields. An asymmetric irid- ium-ca...An iridium-catalyzed allylic substitution of sodium phenyl selenide with unsymmetrical allyl carbonates was accomplished, which produced the linear allyl phenyl selenides in 38%--74% yields. An asymmetric irid- ium-catalyzed allylation of sodium phenyl selenide was presented as well.展开更多
文摘An iridium-catalyzed allylic substitution of sodium phenyl selenide with unsymmetrical allyl carbonates was accomplished, which produced the linear allyl phenyl selenides in 38%--74% yields. An asymmetric irid- ium-catalyzed allylation of sodium phenyl selenide was presented as well.