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重整催化剂优化进展
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作者 郝镇齐 《石油石化绿色低碳》 CAS 2023年第5期82-83,共2页
据报道,在能源转型背景下,汽油需求将下降,但催化重整仍将是全球炼厂生产高辛烷值汽油和芳烃的关键过程。高辛烷值汽油满足高压缩比发动机需求,可以提高燃油车效率。炼厂将面临处理更困难的挑战,需要更高精确度并改进催化剂配方。此外,... 据报道,在能源转型背景下,汽油需求将下降,但催化重整仍将是全球炼厂生产高辛烷值汽油和芳烃的关键过程。高辛烷值汽油满足高压缩比发动机需求,可以提高燃油车效率。炼厂将面临处理更困难的挑战,需要更高精确度并改进催化剂配方。此外,通过催化重整装置产生芳烃作为石化原料可为减小炼厂范围排放提供可行的减排方案。重整装置的副产氢气仍将是加氢装置的重要原料,特别是当更难处理的生物柴油混合在汽油中。增加辛烷值和芳烃的主要方法是将石蜡和环烷烃转化为芳烃。为了实现该目标,在固定床或移动床反应器中采用了专用的多功能贵金属催化剂。 展开更多
关键词 高辛烷值汽油 催化重整装置 重整催化剂 加氢装置 移动床反应器 辛烷值 贵金属催化剂 石化原料
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Tuning the Mottness in Sr_(3)Ir_(2)O_(7)via Bridging Oxygen Vacancies
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作者 徐妙 邹昌炜 +8 位作者 龚本超 贾可 叶树森 郝镇齐 刘凯 石友国 卢仲毅 蔡鹏 王亚愚 《Chinese Physics Letters》 SCIE EI CAS CSCD 2023年第3期25-30,共6页
The electronic evolution of Mott insulators into exotic correlated phases remains puzzling,because of electron interaction and inhomogeneity.Introduction of individual imperfections in Mott insulators could help captu... The electronic evolution of Mott insulators into exotic correlated phases remains puzzling,because of electron interaction and inhomogeneity.Introduction of individual imperfections in Mott insulators could help capture the main mechanism and serve as a basis to understand the evolution.Here we utilize scanning tunneling microscopy to probe the atomic scale electronic structure of the spin-orbit-coupling assisted Mott insulator Sr_(3)Ir_(2)O_(7).It is found that the tunneling spectra exhibit a homogeneous Mott gap in defect-free regions,but near the oxygen vacancy in the rotated Ir O_(2)plane the local Mott gap size is significantly enhanced.We attribute the enhanced gap to the locally reduced hopping integral between the 5d electrons of neighboring Ir sites via the bridging planar oxygen p orbitals.Such bridging defects have a dramatic influence on local bandwidth,thus provide a new way to manipulate the strength of Mottness in a Mott insulator. 展开更多
关键词 BRIDGING TUNNELING utilize
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Machine learning identification of impurities in the STM images 被引量:1
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作者 王策 李海威 +6 位作者 郝镇齐 李昕彤 邹昌炜 蔡鹏 王亚愚 尤亦庄 翟荟 《Chinese Physics B》 SCIE EI CAS CSCD 2020年第11期81-85,共5页
We train a neural network to identify impurities in the experimental images obtained by the scanning tunneling microscope(STM)measurements.The neural network is first trained with a large number of simulated data and ... We train a neural network to identify impurities in the experimental images obtained by the scanning tunneling microscope(STM)measurements.The neural network is first trained with a large number of simulated data and then the trained neural network is applied to identify a set of experimental images taken at different voltages.We use the convolutional neural network to extract features from the images and also implement the attention mechanism to capture the correlations between images taken at different voltages.We note that the simulated data can capture the universal Friedel oscillation but cannot properly describe the non-universal physics short-range physics nearby an impurity,as well as noises in the experimental data.And we emphasize that the key of this approach is to properly deal with these differences between simulated data and experimental data.Here we show that even by including uncorrelated white noises in the simulated data,the performance of the neural network on experimental data can be significantly improved.To prevent the neural network from learning unphysical short-range physics,we also develop another method to evaluate the confidence of the neural network prediction on experimental data and to add this confidence measure into the loss function.We show that adding such an extra loss function can also improve the performance on experimental data.Our research can inspire future similar applications of machine learning on experimental data analysis. 展开更多
关键词 scanning tunneling microscope neural network ATTENTION data regularization
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AlO_x/LiF composite protection layer for Cr-doped(Bi,Sb)_2Te_3 quantum anomalous Hall films
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作者 欧云波 冯洋 +7 位作者 冯硝 郝镇齐 张立果 刘畅 王亚愚 何珂 马旭村 薛其坤 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第8期10-14,共5页
We have realized robust quantum anomalous Hall samples by protecting Cr-doped(Bi,Sb)2Te3 topological insulator films with a combination of LiF and A1Ox capping layers.The AlOx/LiF composite capping layer well keeps ... We have realized robust quantum anomalous Hall samples by protecting Cr-doped(Bi,Sb)2Te3 topological insulator films with a combination of LiF and A1Ox capping layers.The AlOx/LiF composite capping layer well keeps the quantum anomalous Hall states of Cr-doped(Bi,Sb)2Te3 films and effectively prevent them from degradation induced by ambient conditions.The progress is a key step towards the realization of the quantum phenomena in heterostructures and devices based on quantum anomalous Hall system. 展开更多
关键词 quantum anomalous Hall effect AlOx LiE protection layer
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