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共沉淀法制备复合钙钛矿结构PLZST的研究 被引量:9
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作者 薛丽红 张一玲 +2 位作者 李强 郭泉泳 刘锐 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2004年第3期566-570,共5页
用改进的化学共沉淀法制备PLZST前驱体,讨论了共沉淀的最佳pH值范围.通过DTA-TG和XRD详细研究相组成随煅烧温度的变化,并通过和固相合成PLZST多晶料的条件比较可知,共沉淀法合成PLZST多晶料具有纯度高、组份均匀、合成温度低等特点.研... 用改进的化学共沉淀法制备PLZST前驱体,讨论了共沉淀的最佳pH值范围.通过DTA-TG和XRD详细研究相组成随煅烧温度的变化,并通过和固相合成PLZST多晶料的条件比较可知,共沉淀法合成PLZST多晶料具有纯度高、组份均匀、合成温度低等特点.研究表明在700℃低温下即能合成纯钙钛矿相PLZST多晶料.利用化学分析法测定不同温度下合成的PLZST的铅含量表明低温下合成的PLZST,铅挥发量极少,不会由于铅的挥发造成计量比的改变和形成杂相. 展开更多
关键词 化学共沉淀 PLZST 钙钛矿相
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Low Temperature Synthesis of (Pb,La)(Zr,Sn,Ti)O_3 Powders by Citrate Process
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作者 郭泉泳 李强 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2007年第3期526-528,共3页
Lead lanthanum zirconate stannate titanate (PLZST) powders with homogeneous composition were synthesized at a relatively low temperature of 650 ℃ by a citrate process based on the Pechini method. Clear aqueous solu... Lead lanthanum zirconate stannate titanate (PLZST) powders with homogeneous composition were synthesized at a relatively low temperature of 650 ℃ by a citrate process based on the Pechini method. Clear aqueous solutions were prepared from inorganic salts, and citric acid was added as a chelating agent to attain precursor sols. Dried gel-precursors were calcined at different temperatures for various time. The perovskites powders were obtained at 650 ℃ for 1 hour. XRD and SEM results show that the powders were single-phase and ultrafine particles. 展开更多
关键词 PEROVSKITE citrate process Pechini method
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