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6-氯哒嗪-3-羧酸甲酯的合成研究
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作者 赵春深 梁新霞 +1 位作者 解海 金沧 《广东化工》 CAS 2011年第3期71-71,74,共2页
文章介绍了目标化合物6-氯哒嗪-3-羧酸甲酯方便的、高产率的合成方法。本方法以α-酮戊二酸,水合肼作为起始原料,经环合反应、与溴素反应、酯化反应、氯代反应4步,合成了目标化合物,并经IR和1HNMR等对其结构进行了表征。该合成路线原料... 文章介绍了目标化合物6-氯哒嗪-3-羧酸甲酯方便的、高产率的合成方法。本方法以α-酮戊二酸,水合肼作为起始原料,经环合反应、与溴素反应、酯化反应、氯代反应4步,合成了目标化合物,并经IR和1HNMR等对其结构进行了表征。该合成路线原料易得,操作简便,且反应条件温和,适合工业化生产,反应总收率为64.8%。 展开更多
关键词 Α-酮戊二酸 中间体 药物合成 6-氯哒嗪-3-羧酸甲酯
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Investigation on bismuth-oxide photonic crystal fiber for optical parametric amplification
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作者 金沧 饶岚 +2 位作者 苑金辉 申向伟 余重秀 《Optoelectronics Letters》 EI 2011年第3期194-197,共4页
A hexagonal solid-core bismuth-oxide micro-structure fiber is developed to balance its dispersion and nonlinearity.This simulation and calculation results show that the bismuth-oxide photonic crystal fiber(Bi-PCF) has... A hexagonal solid-core bismuth-oxide micro-structure fiber is developed to balance its dispersion and nonlinearity.This simulation and calculation results show that the bismuth-oxide photonic crystal fiber(Bi-PCF) has near zero dispersion around 1550 nm.Its dispersion slop in the communication wavelength range is also relatively flat.Moreover,both nonlinear coefficient and model field distribution are obtained.Compared with the experimental results by SiO2-PCF,it can be seen that the Bi-PCF shows excellent characteristics for the optical parametric amplification(OPA). 展开更多
关键词 AMPLIFICATION BISMUTH Crystal structure Crystal whiskers Dispersion (waves) Optical frequency conversion Photonic crystals Silicon compounds
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Time-stretch analog-to-digital conversion with a photonic crystal fiber 被引量:2
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作者 滕云 余重秀 +3 位作者 苑金辉 陈静轩 金沧 许谦 《Optoelectronics Letters》 EI 2011年第2期143-146,共4页
All-optical analog-to-digital conversion (ADC) has been extensively researched to break through the inherently limited operating speed of electronic devices. In this paper, we use the photonic crystal fiber (PCF) for ... All-optical analog-to-digital conversion (ADC) has been extensively researched to break through the inherently limited operating speed of electronic devices. In this paper, we use the photonic crystal fiber (PCF) for time-stretch (TS) analog-to-digital (A/D) conversion system through generating low noise, linear chirp distribution and flat super-continuum (SC). Based on the radio frequency (RF) analog signal modulated to the linearly chirped super-continuum, the large-dispersion photonic crystal fiber is used for time-domain stretching. 展开更多
关键词 Analog to digital conversion Crystal whiskers Digital devices Electric converters Nonlinear optics Photonic crystals Time varying systems
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Label swapping and packet transmission of DPSK-labeled PPM signal in optical label switching 被引量:1
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作者 师严 张琦 +3 位作者 余重秀 忻向军 金沧 周锐 《Chinese Optics Letters》 SCIE EI CAS CSCD 2011年第8期11-15,共5页
A label swapping scheme of an optical labeled signal with differential phase shift keying (DPSK) for label at 2.5 Gb/s and pulse position modulation (PPM) for payload at 40 Gb/s is demonstrated by simulation. Powe... A label swapping scheme of an optical labeled signal with differential phase shift keying (DPSK) for label at 2.5 Gb/s and pulse position modulation (PPM) for payload at 40 Gb/s is demonstrated by simulation. Power penalties of -1.8 and -0.8 dB are achieved for both the payload and label over 80-kin single mode fiber (SMF) transmission. This labeling scheme allows the use of four-wave mixing (FWM) in semiconductor optical amplifier (SOA) to perform label erasure, with advantages of transparence for bit rate, high processing rate, simple architecture, and low cost. Label swapping is demonstrated with appropriate penalties of -3.5 and 0.8 dB for PPM payload and new DPSK label, respectively. To further prove the effectiveness of the proposed scheme, label swapping in the case of using 10-Gb/s DPSK label is also investigated with the nnwer penaltios af tq n.nd P dR fnr PPM paylnnrl and new dPRIC lnhol 展开更多
关键词 Four wave mixing Light amplifiers Pulse position modulation Single mode fibers
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