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1-{4-[(2-氰基亚胺基-1,3-噻唑烷-3-基)甲基]-噻唑-2-基}-3-取代苯甲酰基脲类化合物的合成及其生物活性 被引量:7
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作者 戴红 赵元飞 +4 位作者 牛平 钱翊钧 李永强 方建新 石玉军 《有机化学》 SCIE CAS CSCD 北大核心 2013年第7期1568-1572,共5页
为了从噻唑类化合物中寻找新的活性物质,利用4-[(2-氰基亚胺基-1,3-噻唑烷-3-基)甲基]-2-氨基噻唑与芳酰基异氰酸酯的缩合反应,合成了一系列未见文献报道的新型含酰基脲结构的噻唑类衍生物6.经1H NMR,MS和元素分析对所有目标化合物的结... 为了从噻唑类化合物中寻找新的活性物质,利用4-[(2-氰基亚胺基-1,3-噻唑烷-3-基)甲基]-2-氨基噻唑与芳酰基异氰酸酯的缩合反应,合成了一系列未见文献报道的新型含酰基脲结构的噻唑类衍生物6.经1H NMR,MS和元素分析对所有目标化合物的结构进行了表征,此外,经13C NMR进一步证实了化合物6a,6e及6h的结构.初步生物活性试验结果表明,在浓度为50μg/mL时,部分目标化合物表现出一定的杀菌活性.如化合物6d对小麦赤霉的抑制率为65.3%;化合物6f对花生褐斑的抑制率为67.3%;化合物6g对苹果轮纹的抑制率为56.1%. 展开更多
关键词 酰基脲 噻唑 合成 生物活性
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Packed anode derived from cocklebur fruit for improving long-term performance of microbial fuel cells
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作者 Cuicui Yans Mengjie Chen +5 位作者 Yijun Qian Lu Zhang Min Lu Xiaoji Xie Ling Huang Wei Huang 《Science China Materials》 SCIE EI CSCD 2019年第5期645-652,共8页
Packed anode of microbial fuel cells(MFCs),commonly with a dense structure, suffers from the clogging,resulting in unsatisfied long-term stability of MFCs. Herein,we fabricate a biochar-based packed anode with a loose... Packed anode of microbial fuel cells(MFCs),commonly with a dense structure, suffers from the clogging,resulting in unsatisfied long-term stability of MFCs. Herein,we fabricate a biochar-based packed anode with a loose structure to enhance the long-term performance of MFCs equipped with packed anodes. The biochar, derived from cocklebur fruit, endows the packed anode with a loose structure but excellent conductivity. Once incorporated into MFCs, the biochar-based packed anode can yield comparable performance to benchmark materials. Particularly, the biochar-based MFCs present no obvious decrease of the power output during 150 days’ operation, which is attributed to the clogging-resistant effect induced by the loose structure of biochar-based anode. The cocklebur fruit-derived biochar can be a promising candidate for MFC anodes, and should facilitate both scaling-up and practical applications of MFCs. 展开更多
关键词 microbial fuel cells BIOCHAR cocklebur fruit packed anode long-term stability
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