As a continuation of the investigation on 1,2-migration of metal carbene and free carbene, two X-ray structures of β-substituted α-diazocarbonyl compounds were obtained. The relationship between the structure and 1,...As a continuation of the investigation on 1,2-migration of metal carbene and free carbene, two X-ray structures of β-substituted α-diazocarbonyl compounds were obtained. The relationship between the structure and 1,2-migratory aptitude was discussed and an exploratory photochemical study of the diazo compounds presented.展开更多
基金Project supported by the National Natural Science Foundation of China (Nos. 20225205, 20390050).
文摘As a continuation of the investigation on 1,2-migration of metal carbene and free carbene, two X-ray structures of β-substituted α-diazocarbonyl compounds were obtained. The relationship between the structure and 1,2-migratory aptitude was discussed and an exploratory photochemical study of the diazo compounds presented.