Glass-ceramic materials were developed as a sealant in the solid oxide fuel cell （SOFC） in the temperature range of 800 -850 ℃. The glass materials were based on the glass and glass-ceramic in the BaO-CaO-Al2O3-SiO...Glass-ceramic materials were developed as a sealant in the solid oxide fuel cell （SOFC） in the temperature range of 800 -850 ℃. The glass materials were based on the glass and glass-ceramic in the BaO-CaO-Al2O3-SiO2-La2O3-B2O3 system. The thermal expansion coefficient （TEC） decreased with lower Ba^2＋ content and higher Ca^2＋ content, but the glass transition temperature and crystallization temperature increased greatly with an increase in Ca^2＋ content and a decrease in Ba^2＋ content, when the other components in the sealant were invariable. The TEC of the sealant with Ba^2＋ content of 25.4% was 10.8 × 10^-6 K^- 1（temperature range from 25 to 850℃）, and its softening temperature was 950 ℃. The TEC of the sealant accorded well with that of La0.9Sr0.1Ga0.5Mg0.2o3- 6（LSGM） with a mismatch of only 3%. The sealant had superior stability and compatibility with the LSGM electrolyte during the process of operation in SOFC. The weight loss of the sealant with Ba^2＋ content of 25.4% was approfimately zero after heat-treated at 800℃ for 500 h in H2 and O2 atmosphere, respectively.展开更多
基金Project supported by National Natural Science Foundation of China (90510006)
文摘Glass-ceramic materials were developed as a sealant in the solid oxide fuel cell （SOFC） in the temperature range of 800 -850 ℃. The glass materials were based on the glass and glass-ceramic in the BaO-CaO-Al2O3-SiO2-La2O3-B2O3 system. The thermal expansion coefficient （TEC） decreased with lower Ba^2＋ content and higher Ca^2＋ content, but the glass transition temperature and crystallization temperature increased greatly with an increase in Ca^2＋ content and a decrease in Ba^2＋ content, when the other components in the sealant were invariable. The TEC of the sealant with Ba^2＋ content of 25.4% was 10.8 × 10^-6 K^- 1（temperature range from 25 to 850℃）, and its softening temperature was 950 ℃. The TEC of the sealant accorded well with that of La0.9Sr0.1Ga0.5Mg0.2o3- 6（LSGM） with a mismatch of only 3%. The sealant had superior stability and compatibility with the LSGM electrolyte during the process of operation in SOFC. The weight loss of the sealant with Ba^2＋ content of 25.4% was approfimately zero after heat-treated at 800℃ for 500 h in H2 and O2 atmosphere, respectively.
