A new heterometallic lanthanide-titanium-organic compound:[Eu_(2)Ti_(2)(dip)_(6)(dig)_(2)(H_(3)0)_(2)].solvent(1,dip=diphenylglycolic acid,dig=diglycolic acid)has been synthesized under solvothermal conditions.Compoun...A new heterometallic lanthanide-titanium-organic compound:[Eu_(2)Ti_(2)(dip)_(6)(dig)_(2)(H_(3)0)_(2)].solvent(1,dip=diphenylglycolic acid,dig=diglycolic acid)has been synthesized under solvothermal conditions.Compound 1 contains a tetra-nuclear{Eu_(2)Ti_(2)}unit with the mixed ligands of dip and dig.Compound 1 displays intense red luminescence.Furthermore,the IR,PXRD,UV-vis and TGA spectra were also studied.展开更多
(Under solvothermal conditions with the mixed solvents of C_(2)H_(5)OH and H_(2)O,a new heterometallic lanthanide-titanium-organic compound,[TbTi(μ3-O)(L_(3))(H_(2)O)_(4)]·H_(3)O(1,H_(2)L=diphenylglycolic acid),...(Under solvothermal conditions with the mixed solvents of C_(2)H_(5)OH and H_(2)O,a new heterometallic lanthanide-titanium-organic compound,[TbTi(μ3-O)(L_(3))(H_(2)O)_(4)]·H_(3)O(1,H_(2)L=diphenylglycolic acid),has been synthesized.Compound 1 exhibits a 3D supramolecular framework by incorporating the tetra-nuclear[Tb_(2)Ti_(2)(μ3-O)2]unit and L^(2-)ligand.Compound 1 shows intense green luminescence.Furthermore,the PXRD,TGA and IR spectra were also studied.)展开更多
文摘A new heterometallic lanthanide-titanium-organic compound:[Eu_(2)Ti_(2)(dip)_(6)(dig)_(2)(H_(3)0)_(2)].solvent(1,dip=diphenylglycolic acid,dig=diglycolic acid)has been synthesized under solvothermal conditions.Compound 1 contains a tetra-nuclear{Eu_(2)Ti_(2)}unit with the mixed ligands of dip and dig.Compound 1 displays intense red luminescence.Furthermore,the IR,PXRD,UV-vis and TGA spectra were also studied.
文摘(Under solvothermal conditions with the mixed solvents of C_(2)H_(5)OH and H_(2)O,a new heterometallic lanthanide-titanium-organic compound,[TbTi(μ3-O)(L_(3))(H_(2)O)_(4)]·H_(3)O(1,H_(2)L=diphenylglycolic acid),has been synthesized.Compound 1 exhibits a 3D supramolecular framework by incorporating the tetra-nuclear[Tb_(2)Ti_(2)(μ3-O)2]unit and L^(2-)ligand.Compound 1 shows intense green luminescence.Furthermore,the PXRD,TGA and IR spectra were also studied.)