Energy conversion efficiency of the dye-sensitized solar cell is improved from 3.5% to 4.5% by adding a small amount of CuI into an ionic liquid electrolyte. It is found that other copper-I salts, for example, CuBr, h...Energy conversion efficiency of the dye-sensitized solar cell is improved from 3.5% to 4.5% by adding a small amount of CuI into an ionic liquid electrolyte. It is found that other copper-I salts, for example, CuBr, have the same effect for the dye-sensitized solar cell. Experimental results show that no Cu^2+ ions exist in this electrolyte. It is suggested that this improvement is caused by the adsorption of Cu^+ onto the TiO2 porous film.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 20673141, the National Basic Research Programme of China under Grant No 2006CB202606, the National High Technology Research and Development Programme of China under Grant No 2006AA03Z341, and the 100-Talents Project of Chinese Academy of Sciences.
文摘Energy conversion efficiency of the dye-sensitized solar cell is improved from 3.5% to 4.5% by adding a small amount of CuI into an ionic liquid electrolyte. It is found that other copper-I salts, for example, CuBr, have the same effect for the dye-sensitized solar cell. Experimental results show that no Cu^2+ ions exist in this electrolyte. It is suggested that this improvement is caused by the adsorption of Cu^+ onto the TiO2 porous film.