Li1.06Co0.05Cr0.1Mn1.85O4 powders were prepared by heating metal-urea nitrate complexes precursors. The influence of synthesis conditions on the structural and electrochemical properties of Li1.06Co0.05Cr0.1Mn1.85O4 w...Li1.06Co0.05Cr0.1Mn1.85O4 powders were prepared by heating metal-urea nitrate complexes precursors. The influence of synthesis conditions on the structural and electrochemical properties of Li1.06Co0.05Cr0.1Mn1.85O4 was investigated by X-ray diffraction, scanning electron microscopy and charge-discharge experiments. The powders were well crystallized and with a narrow particle size distribution and regular morphology about 60 nm. Electrochemical performances indicated that Li1.06Co0.05Cr0.1Mn1.85O4 delivered a high capacity of 191 mAh·g-1 at 14th cycle due to additional 3 V (vs Li) plateau, 145 mAh·g-1 at 22st cycle. The results show that there are two pairs of voltammetric wave (centered at 4 V (vs Li)) and a pairs of voltammetric wave (centered at 3 V (vs Li)), indicating an excellent reversibility.展开更多
文摘Li1.06Co0.05Cr0.1Mn1.85O4 powders were prepared by heating metal-urea nitrate complexes precursors. The influence of synthesis conditions on the structural and electrochemical properties of Li1.06Co0.05Cr0.1Mn1.85O4 was investigated by X-ray diffraction, scanning electron microscopy and charge-discharge experiments. The powders were well crystallized and with a narrow particle size distribution and regular morphology about 60 nm. Electrochemical performances indicated that Li1.06Co0.05Cr0.1Mn1.85O4 delivered a high capacity of 191 mAh·g-1 at 14th cycle due to additional 3 V (vs Li) plateau, 145 mAh·g-1 at 22st cycle. The results show that there are two pairs of voltammetric wave (centered at 4 V (vs Li)) and a pairs of voltammetric wave (centered at 3 V (vs Li)), indicating an excellent reversibility.
